An adduct between tetraammine(1,10-phenanthroline)ruthenium(II) and dibenzo-42-crown-14

Dong I. Yoon; Suzanne Bélanger; Joseph T Hupp; Charlotte L. Stern

doi:10.1107/S010827019800554X

An adduct between tetraammine(1,10-phenanthroline)ruthenium(II) and dibenzo-42-crown-14

Dong I. Yoon^*, Suzanne Bélanger, Joseph T Hupp, Charlotte L. Stern

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The crystal structure of the adduct dibenzo-42-crown-14 (OC-6-22)-tetraammine( 1,10-phenanthroline-N,N′)-ruthenium(II) bis(hexafluorophosphate) dichloromethane solvate, [Ru(C₁₂H₈N₂)(NH₃) ₄](PF₆)₂.C₃₆H₅₆O ₁₄.CH₂-Cl₂, is reported. The guest Ru complex is located deep within the U-shaped cavity formed by folding of the flexible crown host. The ammine ligands of the Ru complex participate in an extensive network of hydrogen bonds with the ether O atoms of the crown. Weak π stacking appears to occur between the aromatic rings of the phenanthroline ligand and the benzene groups of the crown ether.

Original language	English (US)
Pages (from-to)	1427-1431
Number of pages	5
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	10
DOIs	https://doi.org/10.1107/S010827019800554X
State	Published - Oct 15 1998

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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10.1107/S010827019800554X

Cite this

@article{e1aeb8fa9348452a8cdd9621472d105a,

title = "An adduct between tetraammine(1,10-phenanthroline)ruthenium(II) and dibenzo-42-crown-14",

abstract = "The crystal structure of the adduct dibenzo-42-crown-14 (OC-6-22)-tetraammine( 1,10-phenanthroline-N,N′)-ruthenium(II) bis(hexafluorophosphate) dichloromethane solvate, [Ru(C12H8N2)(NH3) 4](PF6)2.C36H56O 14.CH2-Cl2, is reported. The guest Ru complex is located deep within the U-shaped cavity formed by folding of the flexible crown host. The ammine ligands of the Ru complex participate in an extensive network of hydrogen bonds with the ether O atoms of the crown. Weak π stacking appears to occur between the aromatic rings of the phenanthroline ligand and the benzene groups of the crown ether.",

author = "Yoon, {Dong I.} and Suzanne B{\'e}langer and Hupp, {Joseph T} and Stern, {Charlotte L.}",

year = "1998",

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day = "15",

doi = "10.1107/S010827019800554X",

language = "English (US)",

volume = "54",

pages = "1427--1431",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "10",

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TY - JOUR

T1 - An adduct between tetraammine(1,10-phenanthroline)ruthenium(II) and dibenzo-42-crown-14

AU - Yoon, Dong I.

AU - Bélanger, Suzanne

AU - Hupp, Joseph T

AU - Stern, Charlotte L.

PY - 1998/10/15

Y1 - 1998/10/15

N2 - The crystal structure of the adduct dibenzo-42-crown-14 (OC-6-22)-tetraammine( 1,10-phenanthroline-N,N′)-ruthenium(II) bis(hexafluorophosphate) dichloromethane solvate, [Ru(C12H8N2)(NH3) 4](PF6)2.C36H56O 14.CH2-Cl2, is reported. The guest Ru complex is located deep within the U-shaped cavity formed by folding of the flexible crown host. The ammine ligands of the Ru complex participate in an extensive network of hydrogen bonds with the ether O atoms of the crown. Weak π stacking appears to occur between the aromatic rings of the phenanthroline ligand and the benzene groups of the crown ether.

AB - The crystal structure of the adduct dibenzo-42-crown-14 (OC-6-22)-tetraammine( 1,10-phenanthroline-N,N′)-ruthenium(II) bis(hexafluorophosphate) dichloromethane solvate, [Ru(C12H8N2)(NH3) 4](PF6)2.C36H56O 14.CH2-Cl2, is reported. The guest Ru complex is located deep within the U-shaped cavity formed by folding of the flexible crown host. The ammine ligands of the Ru complex participate in an extensive network of hydrogen bonds with the ether O atoms of the crown. Weak π stacking appears to occur between the aromatic rings of the phenanthroline ligand and the benzene groups of the crown ether.

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DO - 10.1107/S010827019800554X

M3 - Article

AN - SCOPUS:1142291461

SN - 0108-2701

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SP - 1427

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 10

ER -

An adduct between tetraammine(1,10-phenanthroline)ruthenium(II) and dibenzo-42-crown-14

Abstract

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CCDC 130455: Experimental Crystal Structure Determination

Cite this

An adduct between tetraammine(1,10-phenanthroline)ruthenium(II) and dibenzo-42-crown-14

Abstract

ASJC Scopus subject areas

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Other files and links

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CCDC 130455: Experimental Crystal Structure Determination

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