An interdigitated functionally rigid [2]rotaxane

Il Yoon, Ognjen Š Miljanić, Diego Benítez, Saeed I. Khan, J. Fraser Stoddart

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

The synthesis of a functionally rigid [2]rotaxane incorporating π-electron rich 1,5-disubstituted naphthalene (NP) ring systems, encircled by the π-electron deficient tetracationic cyclophane, cyclobis(paraquat-p- phenylene), is described; in the solid state, the molecules of this donor-acceptor [2]rotaxane line themselves up in parallel π-π stacks of alternating NP ring systems and bipyridinium units, affording an interdigitated superstructure.

Original languageEnglish (US)
Pages (from-to)4561-4563
Number of pages3
JournalChemical Communications
Issue number38
DOIs
StatePublished - Oct 3 2008

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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