Abstract
The synthesis of a functionally rigid [2]rotaxane incorporating π-electron rich 1,5-disubstituted naphthalene (NP) ring systems, encircled by the π-electron deficient tetracationic cyclophane, cyclobis(paraquat-p- phenylene), is described; in the solid state, the molecules of this donor-acceptor [2]rotaxane line themselves up in parallel π-π stacks of alternating NP ring systems and bipyridinium units, affording an interdigitated superstructure.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 4561-4563 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Issue number | 38 |
| DOIs | |
| State | Published - 2008 |
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Metals and Alloys
- Materials Chemistry
- Surfaces, Coatings and Films
- Chemistry(all)
- Catalysis
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CCDC 661695: Experimental Crystal Structure Determination
Yoon, I. (Creator), Miljanić, O. Š. (Contributor), Benítez, D. (Contributor), Khan, S. I. (Creator) & Stoddart, J. F. (Creator), Cambridge Crystallographic Data Centre, 2009
DOI: 10.5517/ccq6k0g, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccq6k0g&sid=DataCite
Dataset
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CCDC 661694: Experimental Crystal Structure Determination
Yoon, I. (Creator), Miljanić, O. Š. (Contributor), Benítez, D. (Contributor), Khan, S. I. (Creator) & Stoddart, J. F. (Creator), Cambridge Crystallographic Data Centre, 2009
DOI: 10.5517/ccq6jzd, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccq6jzd&sid=DataCite
Dataset