A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO2. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO2 sorption most likely involve the interpenetrated frameworks moving with respect to each other.
|Original language||English (US)|
|Number of pages||6|
|Journal||Chemistry - A European Journal|
|State||Published - Jan 4 2010|
- Dynamic structures
- Gated sorption
- Metal-organic frameworks
- Porous materials
ASJC Scopus subject areas
- Organic Chemistry
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CCDC 704474: Experimental Crystal Structure Determination
Mulfort, K. L. (Creator), Farha, O. K. (Creator), Malliakas, C. D. (Creator), Kanatzidis, M. (Creator) & Hupp, J. T. (Creator), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccrn1zd, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrn1zd&sid=DataCite