An interpenetrated framework material with hysteretic CO2 uptake

Karen L. Mulfort; Omar K. Farha; Christos D. Malliakas; Mercouri G. Kanatzidis; Joseph T. Hupp

doi:10.1002/chem.200902104

An interpenetrated framework material with hysteretic CO₂ uptake

Karen L. Mulfort, Omar K. Farha, Christos D. Malliakas, Mercouri G. Kanatzidis, Joseph T. Hupp

Chemistry

Research output: Contribution to journal › Article › peer-review

194 Scopus citations

Abstract

A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO₂. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO₂ sorption most likely involve the interpenetrated frameworks moving with respect to each other.

Original language	English (US)
Pages (from-to)	276-281
Number of pages	6
Journal	Chemistry - A European Journal
Volume	16
Issue number	1
DOIs	https://doi.org/10.1002/chem.200902104
State	Published - Jan 4 2010

Keywords

Adsorption
CO
Dynamic structures
Gated sorption
Hysteresis
Metal-organic frameworks
Porous materials

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.200902104

Cite this

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abstract = "A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO2. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO2 sorption most likely involve the interpenetrated frameworks moving with respect to each other.",

keywords = "Adsorption, CO, Dynamic structures, Gated sorption, Hysteresis, Metal-organic frameworks, Porous materials",

author = "Mulfort, {Karen L.} and Farha, {Omar K.} and Malliakas, {Christos D.} and Kanatzidis, {Mercouri G.} and Hupp, {Joseph T.}",

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language = "English (US)",

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AU - Mulfort, Karen L.

AU - Farha, Omar K.

AU - Malliakas, Christos D.

AU - Kanatzidis, Mercouri G.

AU - Hupp, Joseph T.

PY - 2010/1/4

Y1 - 2010/1/4

N2 - A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO2. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO2 sorption most likely involve the interpenetrated frameworks moving with respect to each other.

AB - A new, twofold interpenetrated metal-organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO2. Measurement of the structure by powder X- ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO2 sorption most likely involve the interpenetrated frameworks moving with respect to each other.

KW - Adsorption

KW - CO

KW - Dynamic structures

KW - Gated sorption

KW - Hysteresis

KW - Metal-organic frameworks

KW - Porous materials

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

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ER -

An interpenetrated framework material with hysteretic CO₂ uptake

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 704474: Experimental Crystal Structure Determination

Cite this

An interpenetrated framework material with hysteretic CO2 uptake

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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Fingerprint

Datasets

CCDC 704474: Experimental Crystal Structure Determination

Cite this

An interpenetrated framework material with hysteretic CO₂ uptake