An S = 12 semiquinoid radical-bridged Mn6 wheel complex assembled from an asymmetric redox-active bridging ligand

Ie Rang Jeon; T. David Harris

doi:10.1039/c5cc08482b

An S = 12 semiquinoid radical-bridged Mn₆ wheel complex assembled from an asymmetric redox-active bridging ligand

Ie Rang Jeon, T. David Harris^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The asymmetric redox-active ligand 4,5-bis(pyridine-2-carboxamido)-1,2-catechol (^N,OLH₄) is prepared and metalated to afford the hexanuclear complex [Mn₆(^N,OL)₆]^6-. Structural analysis and magnetic measurements reveal this complex to feature Mn^II ions bridged by ^N,OL^3-· radicals, which are antiferromagnetically coupled to give an S = 12 ground state.

Original language	English (US)
Pages (from-to)	1006-1008
Number of pages	3
Journal	Chemical Communications
Volume	52
Issue number	5
DOIs	https://doi.org/10.1039/c5cc08482b
State	Published - 2016

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c5cc08482b

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@article{831ca3349f954359ae813efddfcb6acc,

title = "An S = 12 semiquinoid radical-bridged Mn6 wheel complex assembled from an asymmetric redox-active bridging ligand",

abstract = "The asymmetric redox-active ligand 4,5-bis(pyridine-2-carboxamido)-1,2-catechol (N,OLH4) is prepared and metalated to afford the hexanuclear complex [Mn6(N,OL)6]6-. Structural analysis and magnetic measurements reveal this complex to feature MnII ions bridged by N,OL3-· radicals, which are antiferromagnetically coupled to give an S = 12 ground state.",

author = "Jeon, {Ie Rang} and Harris, {T. David}",

note = "Funding Information: This research was supported by the National Science Foundation Grant DMR-1351959, the Institute for Sustainability and Energy at Northwestern, and Northwestern University. Purchase of the SQUID magnetometer was supported in part by the International Institute of Nanotechnology. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c5cc08482b",

language = "English (US)",

volume = "52",

pages = "1006--1008",

journal = "Chemical Communications",

issn = "1359-7345",

number = "5",

}

TY - JOUR

T1 - An S = 12 semiquinoid radical-bridged Mn6 wheel complex assembled from an asymmetric redox-active bridging ligand

AU - Jeon, Ie Rang

AU - Harris, T. David

N1 - Funding Information: This research was supported by the National Science Foundation Grant DMR-1351959, the Institute for Sustainability and Energy at Northwestern, and Northwestern University. Purchase of the SQUID magnetometer was supported in part by the International Institute of Nanotechnology. Publisher Copyright: © The Royal Society of Chemistry.

PY - 2016

Y1 - 2016

N2 - The asymmetric redox-active ligand 4,5-bis(pyridine-2-carboxamido)-1,2-catechol (N,OLH4) is prepared and metalated to afford the hexanuclear complex [Mn6(N,OL)6]6-. Structural analysis and magnetic measurements reveal this complex to feature MnII ions bridged by N,OL3-· radicals, which are antiferromagnetically coupled to give an S = 12 ground state.

AB - The asymmetric redox-active ligand 4,5-bis(pyridine-2-carboxamido)-1,2-catechol (N,OLH4) is prepared and metalated to afford the hexanuclear complex [Mn6(N,OL)6]6-. Structural analysis and magnetic measurements reveal this complex to feature MnII ions bridged by N,OL3-· radicals, which are antiferromagnetically coupled to give an S = 12 ground state.

UR - http://www.scopus.com/inward/record.url?scp=84954059129&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84954059129&partnerID=8YFLogxK

U2 - 10.1039/c5cc08482b

DO - 10.1039/c5cc08482b

M3 - Article

C2 - 26593229

AN - SCOPUS:84954059129

SN - 1359-7345

VL - 52

SP - 1006

EP - 1008

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

An S = 12 semiquinoid radical-bridged Mn₆ wheel complex assembled from an asymmetric redox-active bridging ligand

Abstract

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CCDC 1430715: Experimental Crystal Structure Determination

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An S = 12 semiquinoid radical-bridged Mn6 wheel complex assembled from an asymmetric redox-active bridging ligand

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 1430715: Experimental Crystal Structure Determination

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An S = 12 semiquinoid radical-bridged Mn₆ wheel complex assembled from an asymmetric redox-active bridging ligand