The asymmetric redox-active ligand 4,5-bis(pyridine-2-carboxamido)-1,2-catechol (N,OLH4) is prepared and metalated to afford the hexanuclear complex [Mn6(N,OL)6]6-. Structural analysis and magnetic measurements reveal this complex to feature MnII ions bridged by N,OL3-· radicals, which are antiferromagnetically coupled to give an S = 12 ground state.
|Original language||English (US)|
|Number of pages||3|
|State||Published - 2016|
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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CCDC 1430715: Experimental Crystal Structure Determination
Jeon, I. (Creator) & Harris, T. D. (Creator), Cambridge Crystallographic Data Centre, 2015
DOI: 10.5517/cc1k0s3g, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1k0s3g&sid=DataCite