Approaches to Sustainable and Continually Recyclable Cross-Linked Polymers

David J. Fortman, Jacob P. Brutman, Guilhem X. De Hoe, Rachel L. Snyder, William Dichtel*, Marc A. Hillmyer

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

261 Scopus citations


Cross-linked polymers are ubiquitous in daily life, finding applications as tires, insulation, adhesives, automotive parts, and countless other products. The covalent cross-links in these materials render them mechanically robust, chemically resistant, and thermally stable, but they also prevent recycling of these materials into similar-value goods. Furthermore, cross-linked polymers are typically produced from petroleum-based feedstocks, and their hydrocarbon backbones render them nondegradable, making them unsustainable in the long term. In recent years, much effort has focused on the development of recycling strategies for cross-linked polymeric materials. In the following Perspective, we discuss many of these approaches, and highlight efforts to sustainably produce recyclable cross-linked polymers. We present our thoughts on future challenges that must be overcome to enable widespread, viable, and more sustainable and practical implementation of these materials, including the sustainable sourcing of feedstocks, long-term environmental stability of inherently dynamic polymers, and moving toward industrially viable synthesis and reprocessing methods.

Original languageEnglish (US)
Pages (from-to)11145-11159
Number of pages15
JournalACS Sustainable Chemistry and Engineering
Issue number9
StatePublished - Sep 4 2018


  • Covalent adaptable network
  • Degradable
  • Pyrolysis
  • Renewable
  • Reprocessing
  • Solvolysis
  • Thermoset
  • Vitrimer

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment


Dive into the research topics of 'Approaches to Sustainable and Continually Recyclable Cross-Linked Polymers'. Together they form a unique fingerprint.

Cite this