Aromatic hydrocarbon belts

Qing Hui Guo, Yunyan Qiu, Mei Xiang Wang, J. Fraser Stoddart*

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

8 Scopus citations

Abstract

Aromatic hydrocarbon belts (AHCBs) have fascinated scientists for over half a century because of their aesthetically appealing structures and potential applications in the field of carbon nanotechnology. One of the enduring challenges in synthesizing AHCBs is how do we cope with the build-up of energy in the highly strained structures during their synthesis? Successful preparations of AHCBs offer the prospect of providing well-defined templates for the growth of uniform single-walled carbon nanotubes—a long-standing interest in nanocarbon science. In this Review, we revisit the protracted historical background involving the rational design and synthesis of AHCBs and highlight some of the more recent breakthroughs, with emphasis being placed on the different strategies that have been used for building up curved and fused benzenoid rings into molecular belts. We also discuss the scientific challenges in this fledgling field and provide some pointers as to what could transpire in years to come. [Figure not available: see fulltext.]

Original languageEnglish (US)
Pages (from-to)402-419
Number of pages18
JournalNature chemistry
Volume13
Issue number5
DOIs
StatePublished - May 2021

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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