Abstract
The aromatizing ring-closing metathesis has been shown to take place inside an extended porous framework. Employing a combination of solvent-assisted linker exchange and postsynthesis modification using olefin metathesis, the noninterpenetrated SALEM-14 was formed and converted catalytically into PAH-MOF-1 with polycyclic aromatic hydrocarbon (PAH) pillars. The metal-organic framework in SALEM-14 prevents "intermolecular" olefin metathesis from occurring between the pillars in the presence of the first generation Hoveyda-Grubbs catalyst, while favoring the production of a PAH, which can be released from the framework under acidic conditions in dimethylsulfoxide.
Original language | English (US) |
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Pages (from-to) | 14916-14919 |
Number of pages | 4 |
Journal | Journal of the American Chemical Society |
Volume | 135 |
Issue number | 40 |
DOIs | |
State | Published - Oct 9 2013 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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CCDC 950458: Experimental Crystal Structure Determination
Vermeulen, N. A. (Creator), Karagiaridi, O. (Creator), Sarjeant, A. A. (Creator), Stern, C. L. (Creator), Hupp, J. T. (Creator), Farha, O. K. (Creator) & Stoddart, J. F. (Creator), Cambridge Crystallographic Data Centre, 2014
DOI: 10.5517/cc10x0yw, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10x0yw&sid=DataCite
Dataset
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CCDC 950460: Experimental Crystal Structure Determination
Vermeulen, N. A. (Creator), Karagiaridi, O. (Creator), Sarjeant, A. A. (Creator), Stern, C. L. (Creator), Hupp, J. T. (Creator), Farha, O. K. (Creator) & Stoddart, J. F. (Creator), Cambridge Crystallographic Data Centre, 2014
DOI: 10.5517/cc10x10z, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc10x10z&sid=DataCite
Dataset