Aryldiazo Complexes. Resonance Interaction of the N-N Stretching Vibrations with Other Ligand Vibrational Modes

Barry L. Haymore, James A Ibers, Devon W. Meek

Research output: Contribution to journalArticle

72 Scopus citations

Abstract

Extensive isotopic labeling using 2H and 15N shows two or three bands which change frequency and intensity for many aryldiazo-transition metal complexes. This effect is shown to arise from the resonance interaction of v(NN) with weak phenyl vibrational modes. From relative intensities of the respective bands, the unperturbed values of v(NN) are estimated. A new cyclic polyether-benzenediazonium complex has been prepared and is shown to be the first diazo complex in which v(NN) increases upon coordination.

Original languageEnglish (US)
Pages (from-to)541-546
Number of pages6
JournalInorganic Chemistry
Volume14
Issue number3
DOIs
StatePublished - Mar 1 1975

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Aryldiazo Complexes. Resonance Interaction of the N-N Stretching Vibrations with Other Ligand Vibrational Modes'. Together they form a unique fingerprint.

  • Cite this