Assembly and Chiral Memory Effects of Dynamic Macroscopic Supramolecular Helices

Tianyu Yuan, Zhimin Sun, Anthony U. Mu, Minxiang Zeng, Alexander J. Kalin, Zhengdong Cheng, Mark A. Olson*, Lei Fang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

Macroscopic enantiomerically pure helical supramolecular fibers are bottom-up assembled in aqueous media from a chiral π-electron donor template and an achiral π-electron acceptor. The helices can be assembled to the sub-millimeter scale with controlled handedness. These dynamic supramolecular architectures allow for a quantitative exchange of the chiral donor template with achiral analogues. During this process, a chiral memory effect was observed, affording enantiomerically pure helices composed entirely of achiral components.

Original languageEnglish (US)
Pages (from-to)16553-16557
Number of pages5
JournalChemistry - A European Journal
Volume24
Issue number62
DOIs
StatePublished - Nov 7 2018
Externally publishedYes

Keywords

  • chiral memory
  • donor–acceptor systems
  • helical structures
  • self-assembly
  • supramolecular chemistry

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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