TY - JOUR
T1 - Associative substitution reactions in 17 electron organometallic radicals
T2 - Direct observation of the reaction of [(C5H5)Fe(CO) 2]· with P(OMe)3 using very fast time-resolved I.R. spectroscopy
AU - Dixon, Andrew J.
AU - Gravelle, Steven J.
AU - Van De Burgt, Lambertus J.
AU - Poliakoff, Martyn
AU - Turner, James J.
AU - Weitz, Eric
PY - 1987
Y1 - 1987
N2 - Time-resolved i.r. spectroscopy is used to monitor directly the formation of [(C5H5)Fe(CO)P(OMe)3]· in the reaction of P(OMe)3 with [(C5H5)Fe(CO) 2]·, generated by 351 nm photolysis of [{(C5H 5)Fe(CO)2}2] in n-heptane solution at room temperature; the reaction is an associative process with a bimolecular rate constant of 8.9 ± 2.0 × 108 dm3 mol -1 s-1.
AB - Time-resolved i.r. spectroscopy is used to monitor directly the formation of [(C5H5)Fe(CO)P(OMe)3]· in the reaction of P(OMe)3 with [(C5H5)Fe(CO) 2]·, generated by 351 nm photolysis of [{(C5H 5)Fe(CO)2}2] in n-heptane solution at room temperature; the reaction is an associative process with a bimolecular rate constant of 8.9 ± 2.0 × 108 dm3 mol -1 s-1.
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U2 - 10.1039/C39870001023
DO - 10.1039/C39870001023
M3 - Article
AN - SCOPUS:37049082419
SN - 0022-4936
SP - 1023
EP - 1025
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 13
ER -