TY - JOUR
T1 - Autoacceleration in free radical methyl methacrylate polymerization
T2 - the diffusion-limited cause of the gel effect
AU - O'Neil, Gregory A.
AU - Wisnudel, Marc B.
AU - Torkelson, John M
PY - 1998/8/1
Y1 - 1998/8/1
N2 - Isothermal methyl methacrylate (MMA) conversion-time data were obtained via differential scanning calorimetry, equating conversion to relative heat generated during the reaction. Temperatures were calibrated using melt transitions determined at 0.1 - 0.5 C heating rate. Molecular weight averages were determined using gel permeation chromatography and monodisperse PMMA standards.
AB - Isothermal methyl methacrylate (MMA) conversion-time data were obtained via differential scanning calorimetry, equating conversion to relative heat generated during the reaction. Temperatures were calibrated using melt transitions determined at 0.1 - 0.5 C heating rate. Molecular weight averages were determined using gel permeation chromatography and monodisperse PMMA standards.
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M3 - Article
AN - SCOPUS:0032140552
VL - 39
SP - 369
EP - 370
JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
SN - 0032-3934
IS - 2
ER -