Ba4Cr2US9: The first chalcogenide analogue of the perovskite-related (A3A′BO6)m(A 3B3O9)n family

Jiyong Yao; James A Ibers

doi:10.1002/zaac.200800153

Ba₄Cr₂US₉: The first chalcogenide analogue of the perovskite-related (A₃A′BO₆)m(A ₃B₃O₉)_n family

Jiyong Yao, James A Ibers

Chemistry

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The compound Ba₄Cr₂US₉, which crystallizes in space group P321, consists of one-dimensional _∞ ¹[Cr₂US₉ ^8-] chains separated by Ba²⁺ cations. Each one-dimensional chain comprises face-sharing CrS₆ octahedra and US₆ trigonal prisms in the sequence oct oct tp oct oct tp with the U and Cr centers in a linear chain parallel to [001].

Original language	English (US)
Pages (from-to)	1645-1647
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	634
Issue number	10
DOIs	https://doi.org/10.1002/zaac.200800153
State	Published - Aug 1 2008

Keywords

Barium chromium uranium sulfide
Perovskite analogues
Solid-state chemistry

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/zaac.200800153

Cite this

@article{c3bbe5842614484b9385a88490438a92,

title = "Ba4Cr2US9: The first chalcogenide analogue of the perovskite-related (A3A′BO6)m(A 3B3O9)n family",

abstract = "The compound Ba4Cr2US9, which crystallizes in space group P321, consists of one-dimensional ∞ 1[Cr2US9 8-] chains separated by Ba2+ cations. Each one-dimensional chain comprises face-sharing CrS6 octahedra and US6 trigonal prisms in the sequence oct oct tp oct oct tp with the U and Cr centers in a linear chain parallel to [001].",

keywords = "Barium chromium uranium sulfide, Perovskite analogues, Solid-state chemistry",

author = "Jiyong Yao and Ibers, {James A}",

year = "2008",

month = aug,

day = "1",

doi = "10.1002/zaac.200800153",

language = "English (US)",

volume = "634",

pages = "1645--1647",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "10",

}

TY - JOUR

T1 - Ba4Cr2US9

T2 - The first chalcogenide analogue of the perovskite-related (A3A′BO6)m(A 3B3O9)n family

AU - Yao, Jiyong

AU - Ibers, James A

PY - 2008/8/1

Y1 - 2008/8/1

N2 - The compound Ba4Cr2US9, which crystallizes in space group P321, consists of one-dimensional ∞ 1[Cr2US9 8-] chains separated by Ba2+ cations. Each one-dimensional chain comprises face-sharing CrS6 octahedra and US6 trigonal prisms in the sequence oct oct tp oct oct tp with the U and Cr centers in a linear chain parallel to [001].

AB - The compound Ba4Cr2US9, which crystallizes in space group P321, consists of one-dimensional ∞ 1[Cr2US9 8-] chains separated by Ba2+ cations. Each one-dimensional chain comprises face-sharing CrS6 octahedra and US6 trigonal prisms in the sequence oct oct tp oct oct tp with the U and Cr centers in a linear chain parallel to [001].

KW - Barium chromium uranium sulfide

KW - Perovskite analogues

KW - Solid-state chemistry

UR - http://www.scopus.com/inward/record.url?scp=53849087122&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=53849087122&partnerID=8YFLogxK

U2 - 10.1002/zaac.200800153

DO - 10.1002/zaac.200800153

M3 - Article

AN - SCOPUS:53849087122

SN - 0044-2313

VL - 634

SP - 1645

EP - 1647

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 10

ER -