Beyond the Active Site. Cp*ZrMe₃/Sulfated Alumina-Catalyzed Olefin Polymerization Tacticity via Catalyst⋅⋅⋅Surface Ion-Pairing

Keyphrases

• 1-hexene 33%
• 1-hexene Polymerization 33%
• Active Sites 100%
• Atomic Scale 33%
• DFT Analysis 33%
• Enchainment 33%
• Ethylene Polymerization 66%
• Heterogeneous Catalysis 33%
• Homopolymerization 33%
• Ion Pairs 100%
• Isotactic Polymerization 33%
• Isotacticity 33%
• Olefin Polymerization 100%
• Organometallic Compounds 33%
• Polyolefins 33%
• Propylene 100%
• Single-site Heterogeneous Catalysts 33%
• Solid-state NMR Spectroscopy 33%
• Sulfated Alumina 100%
• Surface Binding 33%
• Surface Catalyst 33%
• Tacticity 100%

Chemistry

• 1-Hexene 66%
• Alkene 100%
• Aluminum Oxide 100%
• Copolymerization 33%
• Density Functional Theory 33%
• Ethylene 33%
• Heterogeneous Catalysis 33%
• Heterogeneous Catalyst 33%
• Metallocene 33%
• NMR Spectroscopy 33%
• Polymerization 100%
• Polyolefin 33%
• Propene 100%
• Solid-State NMR 33%

Chemical Engineering

• Catalyst Surface 33%
• Copolymerization 33%
• Ethylene 33%
• Olefin 100%
• Organometallics 33%
• Polymerization 100%
• Polyolefin 33%
• Propylene 100%