Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14

Hongwei Yu, Weiguo Zhang, Joshua Young, James M. Rondinelli*, P. Shiv Halasyamani

*Corresponding author for this work

Research output: Contribution to journalArticle

78 Scopus citations

Abstract

A new ultraviolet nonlinear optical (NLO) material, Pb3Mg3TeP2O14 (PMTP), has been synthesized and characterized. The chiral material exhibits a large second harmonic generation (SHG) response of 13.5 × KDP (600 × α-SiO2), and the shortest absorption edge (250 nm) of reported materials with a strong SHG response (>10 × KDP). PMTP has a three-dimensional crystal structure of corner-shared MgO4, PO4, and TeO6 polyhedra, which form a [TeMg3P2O14] framework. Electronic structure calculations revealed that the stereoactive lone pair on the Pb2+ cation is critical to producing the substantial NLO response and that the NLO activity is further enhanced by the presence of triply bidentate Te6+ cations found in Te-O-O-Pb rings.

Original languageEnglish (US)
Pages (from-to)88-91
Number of pages4
JournalJournal of the American Chemical Society
Volume138
Issue number1
DOIs
StatePublished - Jan 13 2016

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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