Binucleating Macrocyclic [14]N4Ligands and Their Complexes. Synthesis of the Free Ligand 2,3-Dioxo-5,6:13,14-dibenzo-9,10- (4′,5′-dimethylbenzo)-1,4,8,11 -tetraazacyclotetradeca-7,11-diene (L) and of the 7,12-Me2-L Metal Complexes and Derivatives. Crystal Structures and Properties of the [M′][M(7,12-Me2-L)] Complexes (M = Ni(II); M = Co(II); M′ = ZnCl2, M = Ni(II); M′ = [Na(5-crown-15)]+, M = Ni(II); M′ = [(C2H5)4N]+, M = Ni(II))

D. Christodoulou, M. G. Kanatzidis, D. Coucouvanis

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Fingerprint Dive into the research topics of 'Binucleating Macrocyclic [14]N<sub>4</sub>Ligands and Their Complexes. Synthesis of the Free Ligand 2,3-Dioxo-5,6:13,14-dibenzo-9,10- (4′,5′-dimethylbenzo)-1,4,8,11 -tetraazacyclotetradeca-7,11-diene (L) and of the 7,12-Me<sub>2</sub>-L Metal Complexes and Derivatives. Crystal Structures and Properties of the [M′][M(7,12-Me<sub>2</sub>-L)] Complexes (M = Ni(II); M = Co(II); M′ = ZnCl<sub>2</sub>, M = Ni(II); M′ = [Na(5-crown-15)]<sup>+</sup>, M = Ni(II); M′ = [(C<sub>2</sub>H<sub>5</sub>)<sub>4</sub>N]<sup>+</sup>, M = Ni(II))'. Together they form a unique fingerprint.

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