Bispyrrolotetrathiafulvalene-containing [2]catenanes

Michael R. Tomcsi, J. Fraser Stoddart*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

(Figure Presented) Two [2]catenanes incorporating bispyrrolotetrathiafulvalene (BPTTF) and weaker aryl donors, hydroquinone (HQ) and 1,5-dioxynaphthalene (DNP), respectively, have been prepared and characterized. These [2]catenanes show a predominant amount (>95:5) of the co-conformation in which either the HQ or the DNP unit is encircled by a tetracationic cyclophane, cyclobis(paraquat-p-phenylene) (CBPQT4+), contrary to what is observed in systems based on the parent tetrathiafulvalene (TTF). These new [2]catenanes act effectively as molecular switches which are always configured in the "on" state.

Original languageEnglish (US)
Pages (from-to)9335-9338
Number of pages4
JournalJournal of Organic Chemistry
Volume72
Issue number24
DOIs
StatePublished - Nov 23 2007

ASJC Scopus subject areas

  • Organic Chemistry

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