Bithiophenesulfonamide Building Block for π-Conjugated Donor-Acceptor Semiconductors

Ferdinand S. Melkonyan, Wei Zhao, Martin Drees, Nicholas D. Eastham, Matthew J. Leonardi, Melanie R. Butler, Zhihua Chen, Xinge Yu, Robert P.H. Chang, Mark A. Ratner, Antonio F. Facchetti*, Tobin J. Marks

*Corresponding author for this work

Research output: Contribution to journalArticle

38 Scopus citations

Abstract

We report here π-conjugated small molecules and polymers based on the new π-acceptor building block, bithiophenesulfonamide (BTSA). Molecular orbital computations and optical, electrochemical, and crystal structure analyses illuminate the architecture and electronic structure of the BTSA unit versus other acceptor building blocks. Field-effect transistors and photovoltaic cells demonstrate that BTSA is a promising unit for the construction of π-conjugated semiconducting materials.

Original languageEnglish (US)
Pages (from-to)6944-6947
Number of pages4
JournalJournal of the American Chemical Society
Volume138
Issue number22
DOIs
StatePublished - Jun 8 2016

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ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Melkonyan, F. S., Zhao, W., Drees, M., Eastham, N. D., Leonardi, M. J., Butler, M. R., Chen, Z., Yu, X., Chang, R. P. H., Ratner, M. A., Facchetti, A. F., & Marks, T. J. (2016). Bithiophenesulfonamide Building Block for π-Conjugated Donor-Acceptor Semiconductors. Journal of the American Chemical Society, 138(22), 6944-6947. https://doi.org/10.1021/jacs.6b03498