Bulk Properties of the Oxygen Reduction Catalyst SrCo0.9Nb0.1O3-δ

Robert E. Usiskin, Timothy C. Davenport, Richard Y. Wang, Webster Guan, Sossina M. Haile*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The perovskite SrCo0.9Nb0.1O3-δ (SCN) has excellent electrochemical activity toward oxygen reduction, and it is also valuable as a possible model material for other state-of-the-art perovskite catalysts based on strontium and cobalt, such as Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF). Here we report thermogravimetric, conductivity, and diffraction measurements from SCN. We find that the thermodynamic stability limits of SCN are slightly more favorable than those reported for BSCF, although both materials exhibit a slow oxidative partial decomposition under likely operating conditions. In SCN, this decomposition is thermodynamically preferred when the average formal oxidation state of cobalt is greater than ∼3.0+, but due to sluggish kinetics, metastable SCN with higher cobalt valence can be observed. The oxygen stoichiometry 3-δ varies from 2.45 to 2.70 under the conditions studied, 500-1000 °C and 10-4-1 bar O2, which encompass both stable and metastable behavior. The electronic conductivity is p-type and thermally activated, with a value at 600 °C in air of 250 S cm-1, comparable to that of La0.8Sr0.2MnO3-δ. The polaron migration enthalpy decreases linearly from 0.30 to 0.05 eV as 3-δ increases from 2.52 to 2.64. Thermal and chemical expansivities are also reported.

Original languageEnglish (US)
Pages (from-to)2599-2608
Number of pages10
JournalChemistry of Materials
Volume28
Issue number8
DOIs
StatePublished - May 10 2016

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

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