Abstract
Monte Carlo simulation has been used to characterize the capillary force due to the condensation of a liquid meniscus between a tip with a nanoscale asperity and a flat surface. To consider both hydrophobic and hydrophilic molecules coating the tip as a model of dip-pen nanolithography, tips with various wettabilities are studied. The capillary force due to the meniscus is calculated for various saturations (humidities). We have implemented a thermodynamic integration technique that can project the force into energetic and entropic contributions. In most cases, the force is mainly energetic in origin. At the snap-off separation where the meniscus disappears, the tip feels a significant entropic force at high saturation. Our calculation shows nonmonotonic behavior of the pull-off force as a function of saturation, which is in qualitative accord with experiments.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 4 |
| Number of pages | 1 |
| Journal | Physical review letters |
| Volume | 90 |
| Issue number | 15 |
| DOIs | |
| State | Published - 2003 |
ASJC Scopus subject areas
- Physics and Astronomy(all)