Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane

Youn Sang Bae; Omar K. Farha; Alexander M. Spokoyny; Chad A. Mirkin; Joseph T. Hupp; Randall Q. Snurr

doi:10.1039/b805785k

Carborane-based metal-organic frameworks as highly selective sorbents for CO₂ over methane

Youn Sang Bae, Omar K. Farha, Alexander M. Spokoyny, Chad A. Mirkin, Joseph T. Hupp, Randall Q. Snurr

Research output: Contribution to journal › Article › peer-review

355 Scopus citations

Abstract

Separation of CO₂/CH₄ mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO₂ over CH₄ (∼17) are obtained, especially in the material with open metal sites.

Original language	English (US)
Pages (from-to)	4135-4137
Number of pages	3
Journal	Chemical Communications
Issue number	35
DOIs	https://doi.org/10.1039/b805785k
State	Published - 2008

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1039/b805785k

Cite this

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title = "Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane",

abstract = "Separation of CO2/CH4 mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (∼17) are obtained, especially in the material with open metal sites.",

author = "Bae, {Youn Sang} and Farha, {Omar K.} and Spokoyny, {Alexander M.} and Mirkin, {Chad A.} and Hupp, {Joseph T.} and Snurr, {Randall Q.}",

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AU - Mirkin, Chad A.

AU - Hupp, Joseph T.

AU - Snurr, Randall Q.

PY - 2008

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AB - Separation of CO2/CH4 mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO2 over CH4 (∼17) are obtained, especially in the material with open metal sites.

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