Carborane-based pincers: Synthesis and structure of SeBSe and SBS Pd(II) complexes

Alexander M. Spokoyny; Matthew G. Reuter; Charlotte L. Stern; Mark A. Ratner; Tamar Seideman; Chad A. Mirkin

doi:10.1021/ja902526k

Carborane-based pincers: Synthesis and structure of SeBSe and SBS Pd(II) complexes

Alexander M. Spokoyny, Matthew G. Reuter, Charlotte L. Stern, Mark A. Ratner, Tamar Seideman, Chad A. Mirkin

Chemistry

Research output: Contribution to journal › Article › peer-review

118 Scopus citations

Abstract

(Figure Presented) We report the synthesis of several unique, boron-rich pincer complexes derived from mcarborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd?B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron?metal pincer complexes and possesses several interesting electronic properties imposed by the m-carborane cage.

Original language	English (US)
Pages (from-to)	9482-9483
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	27
DOIs	https://doi.org/10.1021/ja902526k
State	Published - Jul 15 2009

ASJC Scopus subject areas

General Chemistry
Biochemistry
Catalysis
Colloid and Surface Chemistry

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10.1021/ja902526k

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title = "Carborane-based pincers: Synthesis and structure of SeBSe and SBS Pd(II) complexes",

abstract = "(Figure Presented) We report the synthesis of several unique, boron-rich pincer complexes derived from mcarborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd?B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron?metal pincer complexes and possesses several interesting electronic properties imposed by the m-carborane cage.",

author = "Spokoyny, {Alexander M.} and Reuter, {Matthew G.} and Stern, {Charlotte L.} and Ratner, {Mark A.} and Tamar Seideman and Mirkin, {Chad A.}",

year = "2009",

month = jul,

day = "15",

doi = "10.1021/ja902526k",

language = "English (US)",

volume = "131",

pages = "9482--9483",

journal = "Journal of the American Chemical Society",

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TY - JOUR

T1 - Carborane-based pincers

T2 - Synthesis and structure of SeBSe and SBS Pd(II) complexes

AU - Spokoyny, Alexander M.

AU - Reuter, Matthew G.

AU - Stern, Charlotte L.

AU - Ratner, Mark A.

AU - Seideman, Tamar

AU - Mirkin, Chad A.

PY - 2009/7/15

Y1 - 2009/7/15

N2 - (Figure Presented) We report the synthesis of several unique, boron-rich pincer complexes derived from mcarborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd?B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron?metal pincer complexes and possesses several interesting electronic properties imposed by the m-carborane cage.

AB - (Figure Presented) We report the synthesis of several unique, boron-rich pincer complexes derived from mcarborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd?B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron?metal pincer complexes and possesses several interesting electronic properties imposed by the m-carborane cage.

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DO - 10.1021/ja902526k

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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ER -

Carborane-based pincers: Synthesis and structure of SeBSe and SBS Pd(II) complexes

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CCDC 745647: Experimental Crystal Structure Determination

CCDC 745646: Experimental Crystal Structure Determination

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Carborane-based pincers: Synthesis and structure of SeBSe and SBS Pd(II) complexes

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CCDC 745647: Experimental Crystal Structure Determination

CCDC 745646: Experimental Crystal Structure Determination

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