Carboxylic acid- and ester-functionalized siloxane scaffolds on glass studied by broadband sum frequency generation

Andrea B. Voges; Hind A. Al-Abadleh; Michael J. Musorrafiti; Paul A. Bertin; Son Binh T. Nguyen; Franz M. Geiger

doi:10.1021/jp046564x

Carboxylic acid- and ester-functionalized siloxane scaffolds on glass studied by broadband sum frequency generation

Andrea B. Voges, Hind A. Al-Abadleh, Michael J. Musorrafiti, Paul A. Bertin, Son Binh T. Nguyen, Franz M. Geiger^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

77 Scopus citations

Abstract

Broadband sum frequency generation has been used to characterize glass surfaces functionalized with siloxanes containing terminal carboxylic acid and ester functional groups. ω-Ester silanes can be used in the preparations of ester-functionalized glass surfaces, which yield acid-functionalized surfaces via hydrolysis. This general methodology can be used in environmental, biochemical, or materials science surface chemistry to generate surfaces with tunable physical and chemical properties. Definitive characterization of these carboxylate-functionalized glass surfaces can be performed in the C-H vibrational frequency region using sum frequency generation.

Original language	English (US)
Pages (from-to)	18675-18682
Number of pages	8
Journal	Journal of Physical Chemistry B
Volume	108
Issue number	48
DOIs	https://doi.org/10.1021/jp046564x
State	Published - Dec 2 2004

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

Access to Document

10.1021/jp046564x

Cite this

@article{5310863356c84f1d951f38d10fb8370f,

title = "Carboxylic acid- and ester-functionalized siloxane scaffolds on glass studied by broadband sum frequency generation",

abstract = "Broadband sum frequency generation has been used to characterize glass surfaces functionalized with siloxanes containing terminal carboxylic acid and ester functional groups. ω-Ester silanes can be used in the preparations of ester-functionalized glass surfaces, which yield acid-functionalized surfaces via hydrolysis. This general methodology can be used in environmental, biochemical, or materials science surface chemistry to generate surfaces with tunable physical and chemical properties. Definitive characterization of these carboxylate-functionalized glass surfaces can be performed in the C-H vibrational frequency region using sum frequency generation.",

author = "Voges, {Andrea B.} and Al-Abadleh, {Hind A.} and Musorrafiti, {Michael J.} and Bertin, {Paul A.} and Nguyen, {Son Binh T.} and Geiger, {Franz M.}",

year = "2004",

month = dec,

day = "2",

doi = "10.1021/jp046564x",

language = "English (US)",

volume = "108",

pages = "18675--18682",

journal = "Journal of Physical Chemistry B",

issn = "1520-6106",

number = "48",

}

TY - JOUR

T1 - Carboxylic acid- and ester-functionalized siloxane scaffolds on glass studied by broadband sum frequency generation

AU - Voges, Andrea B.

AU - Al-Abadleh, Hind A.

AU - Musorrafiti, Michael J.

AU - Bertin, Paul A.

AU - Nguyen, Son Binh T.

AU - Geiger, Franz M.

PY - 2004/12/2

Y1 - 2004/12/2

N2 - Broadband sum frequency generation has been used to characterize glass surfaces functionalized with siloxanes containing terminal carboxylic acid and ester functional groups. ω-Ester silanes can be used in the preparations of ester-functionalized glass surfaces, which yield acid-functionalized surfaces via hydrolysis. This general methodology can be used in environmental, biochemical, or materials science surface chemistry to generate surfaces with tunable physical and chemical properties. Definitive characterization of these carboxylate-functionalized glass surfaces can be performed in the C-H vibrational frequency region using sum frequency generation.

AB - Broadband sum frequency generation has been used to characterize glass surfaces functionalized with siloxanes containing terminal carboxylic acid and ester functional groups. ω-Ester silanes can be used in the preparations of ester-functionalized glass surfaces, which yield acid-functionalized surfaces via hydrolysis. This general methodology can be used in environmental, biochemical, or materials science surface chemistry to generate surfaces with tunable physical and chemical properties. Definitive characterization of these carboxylate-functionalized glass surfaces can be performed in the C-H vibrational frequency region using sum frequency generation.

UR - http://www.scopus.com/inward/record.url?scp=10444227439&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=10444227439&partnerID=8YFLogxK

U2 - 10.1021/jp046564x

DO - 10.1021/jp046564x

M3 - Article

AN - SCOPUS:10444227439

SN - 1520-6106

VL - 108

SP - 18675

EP - 18682

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 48

ER -

Carboxylic acid- and ester-functionalized siloxane scaffolds on glass studied by broadband sum frequency generation

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this