Quasi one-dimensional molecular metals based on metallomacrocycle building blocks were compared. The group of compounds Ni(L)I, where L equals dianion of phthalocyanine (PC), tetrabenzporphyrin (TBP), or triazatetrabenzporphyrin (TATBP), are isoionic and isostructural but the nature of the charge carrier is quite different in each material. The compound Ni(PC)I, Ni(TMP)I, and Ni(OMTBP)I (TMP equals tetramethylporphyrin, OMTBP equals octamethyltetrabenzporphyrin) form an isoionic series where Coulomb correlations are of progressively greater importance.
|Original language||English (US)|
|Number of pages||12|
|Journal||Molecular crystals and liquid crystals|
|State||Published - 1982|
|Event||Proc of the Int Conf on Low-Dimens Conduct, Pt C - Boulder, Colo, USA|
Duration: Aug 9 1981 → Aug 14 1981
ASJC Scopus subject areas