Catalytic Applications of Vanadium: A Mechanistic Perspective

Ryan R. Langeslay; David M. Kaphan; Christopher L. Marshall; Peter C. Stair; Alfred P. Sattelberger; Massimiliano Delferro

doi:10.1021/acs.chemrev.8b00245

Catalytic Applications of Vanadium: A Mechanistic Perspective

Ryan R. Langeslay, David M. Kaphan, Christopher L. Marshall, Peter C. Stair, Alfred P. Sattelberger, Massimiliano Delferro^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Review article

58 Scopus citations

Abstract

The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon-carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.

Original language	English (US)
Pages (from-to)	2128-2191
Number of pages	64
Journal	Chemical Reviews
Volume	119
Issue number	4
DOIs	https://doi.org/10.1021/acs.chemrev.8b00245
State	Published - Feb 27 2019

ASJC Scopus subject areas

Chemistry(all)

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Langeslay, R. R., Kaphan, D. M., Marshall, C. L., Stair, P. C., Sattelberger, A. P., & Delferro, M. (2019). Catalytic Applications of Vanadium: A Mechanistic Perspective. Chemical Reviews, 119(4), 2128-2191. https://doi.org/10.1021/acs.chemrev.8b00245

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