TY - JOUR
T1 - Catalytic Applications of Vanadium
T2 - A Mechanistic Perspective
AU - Langeslay, Ryan R.
AU - Kaphan, David M.
AU - Marshall, Christopher L.
AU - Stair, Peter C.
AU - Sattelberger, Alfred P.
AU - Delferro, Massimiliano
N1 - Funding Information:
This work was supported by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences, under Contract DE-AC02-06CH11357.
Funding Information:
David M. Kaphan is a postdoctoral appointee in the Catalysis Science Program in the Chemical Sciences and Engineering Division at the Argonne National Laboratory. He completed his Ph.D. in 2016 at the University of California−Berkeley in the laboratories of Dean Toste and Ken Raymond, where he was supported by a NSF graduate research fellowship. His research at Argonne National Laboratory is focused on mechanistic investigations of supported organometallic catalysts in order to establish structure activity relationships for metal oxides as ancillary ligands and to understand and leverage metal− surface redox interactions.
Publisher Copyright:
© 2018 American Chemical Society.
PY - 2019/2/27
Y1 - 2019/2/27
N2 - The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon-carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.
AB - The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon-carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.
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U2 - 10.1021/acs.chemrev.8b00245
DO - 10.1021/acs.chemrev.8b00245
M3 - Review article
C2 - 30296048
AN - SCOPUS:85054684316
VL - 119
SP - 2128
EP - 2191
JO - Chemical Reviews
JF - Chemical Reviews
SN - 0009-2665
IS - 4
ER -