Catalytic Applications of Vanadium: A Mechanistic Perspective

Ryan R. Langeslay, David M. Kaphan, Christopher L. Marshall, Peter Stair, Alfred P. Sattelberger, Massimiliano Delferro

Research output: Contribution to journalReview article

7 Citations (Scopus)

Abstract

The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon-carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.

Original languageEnglish (US)
Pages (from-to)2128-2191
Number of pages64
JournalChemical Reviews
Volume119
Issue number4
DOIs
StatePublished - Feb 27 2019

Fingerprint

Vanadium
Carbon
Alkanes
Ring opening polymerization
Alkenes
Dehydrogenation
Ketones
Sulfur
Aldehydes
Catalysis
Hydrogenation
Alcohols
Oxidation
Kinetics

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Langeslay, R. R., Kaphan, D. M., Marshall, C. L., Stair, P., Sattelberger, A. P., & Delferro, M. (2019). Catalytic Applications of Vanadium: A Mechanistic Perspective. Chemical Reviews, 119(4), 2128-2191. https://doi.org/10.1021/acs.chemrev.8b00245
Langeslay, Ryan R. ; Kaphan, David M. ; Marshall, Christopher L. ; Stair, Peter ; Sattelberger, Alfred P. ; Delferro, Massimiliano. / Catalytic Applications of Vanadium : A Mechanistic Perspective. In: Chemical Reviews. 2019 ; Vol. 119, No. 4. pp. 2128-2191.
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Langeslay, RR, Kaphan, DM, Marshall, CL, Stair, P, Sattelberger, AP & Delferro, M 2019, 'Catalytic Applications of Vanadium: A Mechanistic Perspective' Chemical Reviews, vol. 119, no. 4, pp. 2128-2191. https://doi.org/10.1021/acs.chemrev.8b00245

Catalytic Applications of Vanadium : A Mechanistic Perspective. / Langeslay, Ryan R.; Kaphan, David M.; Marshall, Christopher L.; Stair, Peter; Sattelberger, Alfred P.; Delferro, Massimiliano.

In: Chemical Reviews, Vol. 119, No. 4, 27.02.2019, p. 2128-2191.

Research output: Contribution to journalReview article

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Langeslay RR, Kaphan DM, Marshall CL, Stair P, Sattelberger AP, Delferro M. Catalytic Applications of Vanadium: A Mechanistic Perspective. Chemical Reviews. 2019 Feb 27;119(4):2128-2191. https://doi.org/10.1021/acs.chemrev.8b00245