Abstract
The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon-carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2128-2191 |
| Number of pages | 64 |
| Journal | Chemical Reviews |
| Volume | 119 |
| Issue number | 4 |
| DOIs | |
| State | Published - Feb 27 2019 |
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ASJC Scopus subject areas
- Chemistry(all)
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Catalytic Applications of Vanadium : A Mechanistic Perspective. / Langeslay, Ryan R.; Kaphan, David M.; Marshall, Christopher L.; Stair, Peter; Sattelberger, Alfred P.; Delferro, Massimiliano.
In: Chemical Reviews, Vol. 119, No. 4, 27.02.2019, p. 2128-2191.Research output: Contribution to journal › Review article
TY - JOUR
T1 - Catalytic Applications of Vanadium
T2 - A Mechanistic Perspective
AU - Langeslay, Ryan R.
AU - Kaphan, David M.
AU - Marshall, Christopher L.
AU - Stair, Peter
AU - Sattelberger, Alfred P.
AU - Delferro, Massimiliano
PY - 2019/2/27
Y1 - 2019/2/27
N2 - The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon-carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.
AB - The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon-carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.
UR - http://www.scopus.com/inward/record.url?scp=85054684316&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85054684316&partnerID=8YFLogxK
U2 - 10.1021/acs.chemrev.8b00245
DO - 10.1021/acs.chemrev.8b00245
M3 - Review article
VL - 119
SP - 2128
EP - 2191
JO - Chemical Reviews
JF - Chemical Reviews
SN - 0009-2665
IS - 4
ER -