Abstract
Enantioselective conjunctive cross-coupling with propargylic carbonates affords β-boryl allenes as the reaction product. The reaction is found to proceed through the intermediacy of dimethoxyboronate complexes that are generated in situ by a strain-induced ligand exchange reaction.
Original language | English (US) |
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Pages (from-to) | 11381-11385 |
Number of pages | 5 |
Journal | ACS Catalysis |
Volume | 9 |
Issue number | 12 |
DOIs | |
State | Published - Dec 6 2019 |
Funding
This work was supported by the NIH (No. R35-GM1217140). We thank Solvias for a generous donation of MandyPhos ligands. This work was supported by the NIH (No. R35-GM1217140). We thank Solvias for a generous donation of MandyPhos ligands.
ASJC Scopus subject areas
- Catalysis
- General Chemistry