Catalytic Enantioselective Synthesis of β-Allenyl Boronic Esters by Conjunctive Cross-Coupling with Propargylic Carbonates

Mark D. Aparece, Weipeng Hu, James P. Morken*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

20 Scopus citations

Abstract

Enantioselective conjunctive cross-coupling with propargylic carbonates affords β-boryl allenes as the reaction product. The reaction is found to proceed through the intermediacy of dimethoxyboronate complexes that are generated in situ by a strain-induced ligand exchange reaction.

Original languageEnglish (US)
Pages (from-to)11381-11385
Number of pages5
JournalACS Catalysis
Volume9
Issue number12
DOIs
StatePublished - Dec 6 2019

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry

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