@article{eaa88b1839fe47da972678f5c3d2d673,
title = "Catalytic Zirconium/Hafnium-Based Metal-Organic Frameworks",
abstract = "Metal-organic frameworks (MOFs) are highly versatile materials that find applications in several fields. Highly stable zirconium/hafnium-based MOFs were recently introduced and nowadays represent a rapidly growing family. Their unique and intriguing properties make them privileged materials and outstanding candidates in heterogeneous catalysis, finding use either as catalysts or catalyst supports. Various techniques have been developed to incorporate active species into Zr-MOFs, giving rise to catalysts that often demonstrate higher performances or unusual activity when compared with their homogeneous analogues. Catalytic functions are commonly incorporated at the zirconium-oxide node, at the linker, or encapsulated in the pores. Representative examples are discussed, and advantages in adopting Zr- and Hf-MOFs in catalytic applications are highlighted.",
keywords = "catalysis, encapsulation, hafnium, linker, metal{\^a}organic framework, node, zirconium",
author = "Martino Rimoldi and Howarth, {Ashlee J.} and Destefano, {Matthew R.} and Lu Lin and Subhadip Goswami and Peng Li and Hupp, {Joseph T.} and Farha, {Omar K.}",
note = "Funding Information: This work (writing and cited work from NU on catalysis of gas-phase reactions by AIM-based materials) was supported as part of the Inorganometallic Catalysis Design Center, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award No. DE-SC0012702. Work at Northwestern University on electrocatalytic and photocatalytic water oxidation, water reduction, and CO2 reduction was supported as part of the ANSER Center, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science Basic Energy Sciences under Award No. DE-SC0001059. For work done in our own lab, we also gratefully acknowledge the U.S. Defense Threat Reduction Agency and the Army Research Office (grant HDTRA10-1-0023 and project W911NF-13-1-0229; degradation of chemical warfare agents and simulants), the Institute of Catalysis for Energy Processes at Northwestern University (grant DEFG02-03ER15457; vanadium-based catalytic chemistry), the Department of Energy, Office of Science, Separations and Analysis program (grant DE-FG02-08ER15967; MOF synthesis methods) and the National Science Foundation (grant DMR-1334928; nanoparticle/MOF hybrids). M. R. was supported by the Swiss National Science Foundation with an ???Early Postdoc. Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",
year = "2017",
month = feb,
day = "3",
doi = "10.1021/acscatal.6b02923",
language = "English (US)",
volume = "7",
pages = "997--1014",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "American Chemical Society",
number = "2",
}