Cation Distribution and Defect Chemistry of Iron‐Aluminate Spinels

T. O. MASON*, H. K. BOWEN

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

A model describing cation distribution and defect concentrations in iron‐aluminate spinels is presented. Cation distribution equilibrium constants are derived from phase‐boundary data at 1500° and 1280°C. Estimations of the defect concentrations for the entire solid solution are possible using defect equilibrium constants for Fe3O4.

Original languageEnglish (US)
Pages (from-to)86-90
Number of pages5
JournalJournal of the American Ceramic Society
Volume64
Issue number2
DOIs
StatePublished - Jan 1 1981

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

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