Cavity-tailored, self-sorting supramolecular catalytic boxes for selective oxidation

Joong Lee Suk; So Hye Cho; Karen L. Mulfort; David M. Tiede; Joseph T. Hupp; Son Binh T. Nguyen

doi:10.1021/ja804014y

Cavity-tailored, self-sorting supramolecular catalytic boxes for selective oxidation

Joong Lee Suk, So Hye Cho, Karen L. Mulfort, David M. Tiede, Joseph T. Hupp, Son Binh T. Nguyen

Chemistry

Research output: Contribution to journal › Article › peer-review

146 Scopus citations

Abstract

Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by solution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.

Original language	English (US)
Pages (from-to)	16828-16829
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	50
DOIs	https://doi.org/10.1021/ja804014y
State	Published - Dec 17 2008

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja804014y

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abstract = "Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by solution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.",

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AU - Suk, Joong Lee

AU - Cho, So Hye

AU - Mulfort, Karen L.

AU - Tiede, David M.

AU - Hupp, Joseph T.

AU - Nguyen, Son Binh T.

PY - 2008/12/17

Y1 - 2008/12/17

N2 - Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by solution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.

AB - Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by solution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.

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Cavity-tailored, self-sorting supramolecular catalytic boxes for selective oxidation

Abstract

ASJC Scopus subject areas

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