TY - JOUR
T1 - [Ce(PSe4)4]9-
T2 - A highly anionic Ce3+ selenophosphate coordination complex
AU - Chondroudis, Konstantinos
AU - Kanatzidis, Mercouri G.
N1 - Funding Information:
Financial support from the National Science Foundation DMR-9527347 is gratefully acknowledged. This work made use of the SEM and TEM facilities of the Center for Electron Optics at Michigan State University.
Copyright:
Copyright 2017 Elsevier B.V., All rights reserved.
PY - 1998/2/1
Y1 - 1998/2/1
N2 - The reaction of Ce with the basic polychalcophosphate flux Rb10P4Se25 yielded the quaternary selenophosphate compound Rb9Ce(PSe4)4. The discrete [Ce(PSe4)4]9- anion possesses the highest charge observed in a monometallic complex. The Ce3+ center is chelated by four bidentate [PSe4]3- ligands so it achieves a dodecahedral coordination geometry, and the complex belongs to the dodecahedral sub-class Id (D2d-4̄2m), according to the Hoard and Silverton notation. The UV-Vis, optical, IR spectroscopic and magnetism data for the compound are reported.
AB - The reaction of Ce with the basic polychalcophosphate flux Rb10P4Se25 yielded the quaternary selenophosphate compound Rb9Ce(PSe4)4. The discrete [Ce(PSe4)4]9- anion possesses the highest charge observed in a monometallic complex. The Ce3+ center is chelated by four bidentate [PSe4]3- ligands so it achieves a dodecahedral coordination geometry, and the complex belongs to the dodecahedral sub-class Id (D2d-4̄2m), according to the Hoard and Silverton notation. The UV-Vis, optical, IR spectroscopic and magnetism data for the compound are reported.
KW - Anionic complexes
KW - Cerium complexes
KW - Crystal structures
KW - Selenophosphate complexes
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U2 - 10.1016/S1387-7003(98)00011-2
DO - 10.1016/S1387-7003(98)00011-2
M3 - Article
AN - SCOPUS:0001823762
VL - 1
SP - 55
EP - 57
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
IS - 2
ER -