[Ce(PSe4)4]9-: A highly anionic Ce3+ selenophosphate coordination complex

Konstantinos Chondroudis; Mercouri G. Kanatzidis

doi:10.1016/S1387-7003(98)00011-2

[Ce(PSe₄)₄]^9-: A highly anionic Ce³⁺ selenophosphate coordination complex

Konstantinos Chondroudis, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The reaction of Ce with the basic polychalcophosphate flux Rb₁₀P₄Se₂₅ yielded the quaternary selenophosphate compound Rb₉Ce(PSe₄)₄. The discrete [Ce(PSe₄)₄]^9- anion possesses the highest charge observed in a monometallic complex. The Ce³⁺ center is chelated by four bidentate [PSe₄]^3- ligands so it achieves a dodecahedral coordination geometry, and the complex belongs to the dodecahedral sub-class Id (D_2d-4̄2m), according to the Hoard and Silverton notation. The UV-Vis, optical, IR spectroscopic and magnetism data for the compound are reported.

Original language	English (US)
Pages (from-to)	55-57
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	1
Issue number	2
DOIs	https://doi.org/10.1016/S1387-7003(98)00011-2
State	Published - Feb 1 1998

Funding

Financial support from the National Science Foundation DMR-9527347 is gratefully acknowledged. This work made use of the SEM and TEM facilities of the Center for Electron Optics at Michigan State University.

Keywords

Anionic complexes
Cerium complexes
Crystal structures
Selenophosphate complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S1387-7003(98)00011-2

Cite this

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title = "[Ce(PSe4)4]9-: A highly anionic Ce3+ selenophosphate coordination complex",

abstract = "The reaction of Ce with the basic polychalcophosphate flux Rb10P4Se25 yielded the quaternary selenophosphate compound Rb9Ce(PSe4)4. The discrete [Ce(PSe4)4]9- anion possesses the highest charge observed in a monometallic complex. The Ce3+ center is chelated by four bidentate [PSe4]3- ligands so it achieves a dodecahedral coordination geometry, and the complex belongs to the dodecahedral sub-class Id (D2d-{\=4}2m), according to the Hoard and Silverton notation. The UV-Vis, optical, IR spectroscopic and magnetism data for the compound are reported.",

keywords = "Anionic complexes, Cerium complexes, Crystal structures, Selenophosphate complexes",

author = "Konstantinos Chondroudis and Kanatzidis, {Mercouri G.}",

note = "Funding Information: Financial support from the National Science Foundation DMR-9527347 is gratefully acknowledged. This work made use of the SEM and TEM facilities of the Center for Electron Optics at Michigan State University. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.",

year = "1998",

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T2 - A highly anionic Ce3+ selenophosphate coordination complex

AU - Chondroudis, Konstantinos

AU - Kanatzidis, Mercouri G.

N1 - Funding Information: Financial support from the National Science Foundation DMR-9527347 is gratefully acknowledged. This work made use of the SEM and TEM facilities of the Center for Electron Optics at Michigan State University. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.

PY - 1998/2/1

Y1 - 1998/2/1

N2 - The reaction of Ce with the basic polychalcophosphate flux Rb10P4Se25 yielded the quaternary selenophosphate compound Rb9Ce(PSe4)4. The discrete [Ce(PSe4)4]9- anion possesses the highest charge observed in a monometallic complex. The Ce3+ center is chelated by four bidentate [PSe4]3- ligands so it achieves a dodecahedral coordination geometry, and the complex belongs to the dodecahedral sub-class Id (D2d-4̄2m), according to the Hoard and Silverton notation. The UV-Vis, optical, IR spectroscopic and magnetism data for the compound are reported.

AB - The reaction of Ce with the basic polychalcophosphate flux Rb10P4Se25 yielded the quaternary selenophosphate compound Rb9Ce(PSe4)4. The discrete [Ce(PSe4)4]9- anion possesses the highest charge observed in a monometallic complex. The Ce3+ center is chelated by four bidentate [PSe4]3- ligands so it achieves a dodecahedral coordination geometry, and the complex belongs to the dodecahedral sub-class Id (D2d-4̄2m), according to the Hoard and Silverton notation. The UV-Vis, optical, IR spectroscopic and magnetism data for the compound are reported.

KW - Anionic complexes

KW - Cerium complexes

KW - Crystal structures

KW - Selenophosphate complexes

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