Chalcogenide chemistry in ionic liquids: Nonlinear optical wave-mixing properties of the double-cubane compound [Sb7S8Br 2](AlCl4)3

Qichun Zhang; In Chung; Joon I. Jang; John B Ketterson; Mercouri Kanatzidis

doi:10.1021/ja903881m

Chalcogenide chemistry in ionic liquids: Nonlinear optical wave-mixing properties of the double-cubane compound [Sb₇S₈Br ₂](AlCl₄)₃

Qichun Zhang, In Chung, Joon I. Jang, John B Ketterson, Mercouri Kanatzidis

Research output: Contribution to journal › Article › peer-review

228 Scopus citations

Abstract

(Graph Presented) The new cation [Sb₇S₈Br ₂]³⁺ has a double-cubane structure and forms as the [AlCl₄]^- salt from the ionic liquid EMIMBr-AlCl ₃ (EMIM = 1-ethyl-3-methylimidazolium) at 165°C. The compound is noncentrosymmetric with space group P2₁2₁2₁ and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.

Original language	English (US)
Pages (from-to)	9896-9897
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	29
DOIs	https://doi.org/10.1021/ja903881m
State	Published - Jul 29 2009

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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title = "Chalcogenide chemistry in ionic liquids: Nonlinear optical wave-mixing properties of the double-cubane compound [Sb7S8Br 2](AlCl4)3",

abstract = "(Graph Presented) The new cation [Sb7S8Br 2]3+ has a double-cubane structure and forms as the [AlCl4]- salt from the ionic liquid EMIMBr-AlCl 3 (EMIM = 1-ethyl-3-methylimidazolium) at 165°C. The compound is noncentrosymmetric with space group P212121 and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.",

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T2 - Nonlinear optical wave-mixing properties of the double-cubane compound [Sb7S8Br 2](AlCl4)3

AU - Zhang, Qichun

AU - Chung, In

AU - Jang, Joon I.

AU - Ketterson, John B

AU - Kanatzidis, Mercouri

PY - 2009/7/29

Y1 - 2009/7/29

N2 - (Graph Presented) The new cation [Sb7S8Br 2]3+ has a double-cubane structure and forms as the [AlCl4]- salt from the ionic liquid EMIMBr-AlCl 3 (EMIM = 1-ethyl-3-methylimidazolium) at 165°C. The compound is noncentrosymmetric with space group P212121 and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.

AB - (Graph Presented) The new cation [Sb7S8Br 2]3+ has a double-cubane structure and forms as the [AlCl4]- salt from the ionic liquid EMIMBr-AlCl 3 (EMIM = 1-ethyl-3-methylimidazolium) at 165°C. The compound is noncentrosymmetric with space group P212121 and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.

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Chalcogenide chemistry in ionic liquids: Nonlinear optical wave-mixing properties of the double-cubane compound [Sb₇S₈Br ₂](AlCl₄)₃

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