Abstract
It has long been thought that the highly conductive complexes formed between elemental iodine and various polycyclic aromatic hydrocarbons are molecular complexes; i.e., they contain iodine as I2. In this contribution we report resonance Raman and iodine-129 Mössbauer spectroscopic characterization of the form of the iodine in the most highly conductive of these materials : “2Perylene•3I2”. We find that “2Perylene•3I2”is not a molecular complex, but rather a partially oxidized, mixed-valence compound, the charge distribution of which can be approximately formulated on the basis of the spectral data as (perylene)+0.4(I3-•2I2)0.4.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 7568-7573 |
| Number of pages | 6 |
| Journal | Journal of the American Chemical Society |
| Volume | 101 |
| Issue number | 25 |
| DOIs | |
| State | Published - Feb 1 1979 |
Fingerprint
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
Cite this
}
Charge Transfer and Partial Oxidation in the Conductive Hydrocarbon-Iodine Complex “2Perylene•3I2”. / Teitelbaum, Robert C.; Ruby, Stanley L.; Marks, Tobin Jay.
In: Journal of the American Chemical Society, Vol. 101, No. 25, 01.02.1979, p. 7568-7573.Research output: Contribution to journal › Article
TY - JOUR
T1 - Charge Transfer and Partial Oxidation in the Conductive Hydrocarbon-Iodine Complex “2Perylene•3I2”
AU - Teitelbaum, Robert C.
AU - Ruby, Stanley L.
AU - Marks, Tobin Jay
PY - 1979/2/1
Y1 - 1979/2/1
N2 - It has long been thought that the highly conductive complexes formed between elemental iodine and various polycyclic aromatic hydrocarbons are molecular complexes; i.e., they contain iodine as I2. In this contribution we report resonance Raman and iodine-129 Mössbauer spectroscopic characterization of the form of the iodine in the most highly conductive of these materials : “2Perylene•3I2”. We find that “2Perylene•3I2”is not a molecular complex, but rather a partially oxidized, mixed-valence compound, the charge distribution of which can be approximately formulated on the basis of the spectral data as (perylene)+0.4(I3-•2I2)0.4.
AB - It has long been thought that the highly conductive complexes formed between elemental iodine and various polycyclic aromatic hydrocarbons are molecular complexes; i.e., they contain iodine as I2. In this contribution we report resonance Raman and iodine-129 Mössbauer spectroscopic characterization of the form of the iodine in the most highly conductive of these materials : “2Perylene•3I2”. We find that “2Perylene•3I2”is not a molecular complex, but rather a partially oxidized, mixed-valence compound, the charge distribution of which can be approximately formulated on the basis of the spectral data as (perylene)+0.4(I3-•2I2)0.4.
UR - http://www.scopus.com/inward/record.url?scp=33845561594&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33845561594&partnerID=8YFLogxK
U2 - 10.1021/ja00519a017
DO - 10.1021/ja00519a017
M3 - Article
VL - 101
SP - 7568
EP - 7573
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 25
ER -