Charge Transfer and Partial Oxidation in the Conductive Hydrocarbon-Iodine Complex “2Perylene•3I2

Robert C. Teitelbaum, Stanley L. Ruby, Tobin Jay Marks

Research output: Contribution to journalArticle

52 Citations (Scopus)

Abstract

It has long been thought that the highly conductive complexes formed between elemental iodine and various polycyclic aromatic hydrocarbons are molecular complexes; i.e., they contain iodine as I2. In this contribution we report resonance Raman and iodine-129 Mössbauer spectroscopic characterization of the form of the iodine in the most highly conductive of these materials : “2Perylene•3I2”. We find that “2Perylene•3I2”is not a molecular complex, but rather a partially oxidized, mixed-valence compound, the charge distribution of which can be approximately formulated on the basis of the spectral data as (perylene)+0.4(I3-•2I2)0.4.

Original languageEnglish (US)
Pages (from-to)7568-7573
Number of pages6
JournalJournal of the American Chemical Society
Volume101
Issue number25
DOIs
StatePublished - Feb 1 1979

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Hydrocarbons
Iodine
Charge transfer
Oxidation
Perylene
Polycyclic Aromatic Hydrocarbons
Charge distribution
Polycyclic aromatic hydrocarbons

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

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abstract = "It has long been thought that the highly conductive complexes formed between elemental iodine and various polycyclic aromatic hydrocarbons are molecular complexes; i.e., they contain iodine as I2. In this contribution we report resonance Raman and iodine-129 M{\"o}ssbauer spectroscopic characterization of the form of the iodine in the most highly conductive of these materials : “2Perylene•3I2”. We find that “2Perylene•3I2”is not a molecular complex, but rather a partially oxidized, mixed-valence compound, the charge distribution of which can be approximately formulated on the basis of the spectral data as (perylene)+0.4(I3-•2I2)0.4.",
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Charge Transfer and Partial Oxidation in the Conductive Hydrocarbon-Iodine Complex “2Perylene•3I2”. / Teitelbaum, Robert C.; Ruby, Stanley L.; Marks, Tobin Jay.

In: Journal of the American Chemical Society, Vol. 101, No. 25, 01.02.1979, p. 7568-7573.

Research output: Contribution to journalArticle

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