Chemical conversion of biomass-derived hexose sugars to levulinic acid over sulfonic acid-functionalized graphene oxide catalysts

Pravin P. Upare, Ji Woong Yoon, Mi Yeon Kim, Hyo Yoon Kang, Dong Won Hwang, Young Kyu Hwang*, Harold H. Kung, Jong San Chang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

144 Scopus citations

Abstract

Heterogeneous graphene oxide (GO)-based catalysts with sulfonic acid (SO3H) functional groups (GO-SO3H) were used for the selective decomposition of the hexose sugars, glucose and fructose into levulinic acid (LA), which has been used as a platform chemical for various value-added derivatives. The GO-SO3H catalysts gave high yields of around 78% for LA and showed good reuse compatibility with reliable performance. The chemical transformation patterns for hexose sugar decompositions are affected by the temperature, the density of acid sites, and the type of catalyst. The high catalytic performance of GO-SO3H was shown to result from the higher density of Brønsted acid sites in the GO, compared with the Lewis acid sites in other AC-SO3H catalysts. The morphology, surface characteristics, and other physiochemical properties were evaluated using several characterization techniques.

Original languageEnglish (US)
Pages (from-to)2935-2943
Number of pages9
JournalGreen Chemistry
Volume15
Issue number10
DOIs
StatePublished - Oct 2013

ASJC Scopus subject areas

  • Environmental Chemistry
  • Pollution

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