C(i) symmetric and non-centrosymmetric crystalline complexes of [60]fullerene with octakis(dimethylamino)porphyrazinato-copper(II) and - nickel(II)

Detlev H. Hochmuth; Sarah L.J. Michel; Andrew J.P. White; David J. Williams; Anthony G.M. Barrett; Brian M. Hoffman

doi:10.1002/(sici)1099-0682(200004)2000:4<593::aid-ejic593>3.0.co;2-n

C(i) symmetric and non-centrosymmetric crystalline complexes of [60]fullerene with octakis(dimethylamino)porphyrazinato-copper(II) and - nickel(II)

Detlev H. Hochmuth^*, Sarah L.J. Michel, Andrew J.P. White, David J. Williams, Anthony G.M. Barrett, Brian M. Hoffman

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

X-ray structural analysis of octakis(dimethylamino)porphyrazinato- metallo(II)·[60]fullerene complexes (M = Cu²⁺ and Ni²⁺) surprisingly revealed two totally different supramolecular structures, the first exhibiting a C(i) symmetric sandwich complex of two slightly dished porphyrazine units enclosing one fullerene sphere, the other featuring a noncentrosymmetric 1:1 complex with a strongly warped porphyrazine unit.

Original language	English (US)
Pages (from-to)	593-596
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	4
DOIs	https://doi.org/10.1002/(sici)1099-0682(200004)2000:4<593::aid-ejic593>3.0.co;2-n
State	Published - 2000

Keywords

Fullerenes
Porphyrazines

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/(sici)1099-0682(200004)2000:4<593::aid-ejic593>3.0.co;2-n

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Hochmuth, D. H., Michel, S. L. J., White, A. J. P., Williams, D. J., Barrett, A. G. M., & Hoffman, B. M. (2000). C(i) symmetric and non-centrosymmetric crystalline complexes of [60]fullerene with octakis(dimethylamino)porphyrazinato-copper(II) and - nickel(II). European Journal of Inorganic Chemistry, (4), 593-596. https://doi.org/10.1002/(sici)1099-0682(200004)2000:4<593::aid-ejic593>3.0.co;2-n

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title = "C(i) symmetric and non-centrosymmetric crystalline complexes of [60]fullerene with octakis(dimethylamino)porphyrazinato-copper(II) and - nickel(II)",

abstract = "X-ray structural analysis of octakis(dimethylamino)porphyrazinato- metallo(II)·[60]fullerene complexes (M = Cu2+ and Ni2+) surprisingly revealed two totally different supramolecular structures, the first exhibiting a C(i) symmetric sandwich complex of two slightly dished porphyrazine units enclosing one fullerene sphere, the other featuring a noncentrosymmetric 1:1 complex with a strongly warped porphyrazine unit.",

keywords = "Fullerenes, Porphyrazines",

author = "Hochmuth, {Detlev H.} and Michel, {Sarah L.J.} and White, {Andrew J.P.} and Williams, {David J.} and Barrett, {Anthony G.M.} and Hoffman, {Brian M.}",

year = "2000",

doi = "10.1002/(sici)1099-0682(200004)2000:4<593::aid-ejic593>3.0.co;2-n",

language = "English (US)",

pages = "593--596",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "4",

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Hochmuth, DH, Michel, SLJ, White, AJP, Williams, DJ, Barrett, AGM & Hoffman, BM 2000, 'C(i) symmetric and non-centrosymmetric crystalline complexes of [60]fullerene with octakis(dimethylamino)porphyrazinato-copper(II) and - nickel(II)', European Journal of Inorganic Chemistry, no. 4, pp. 593-596. https://doi.org/10.1002/(sici)1099-0682(200004)2000:4<593::aid-ejic593>3.0.co;2-n

TY - JOUR

T1 - C(i) symmetric and non-centrosymmetric crystalline complexes of [60]fullerene with octakis(dimethylamino)porphyrazinato-copper(II) and - nickel(II)

AU - Hochmuth, Detlev H.

AU - Michel, Sarah L.J.

AU - White, Andrew J.P.

AU - Williams, David J.

AU - Barrett, Anthony G.M.

AU - Hoffman, Brian M.

PY - 2000

Y1 - 2000

N2 - X-ray structural analysis of octakis(dimethylamino)porphyrazinato- metallo(II)·[60]fullerene complexes (M = Cu2+ and Ni2+) surprisingly revealed two totally different supramolecular structures, the first exhibiting a C(i) symmetric sandwich complex of two slightly dished porphyrazine units enclosing one fullerene sphere, the other featuring a noncentrosymmetric 1:1 complex with a strongly warped porphyrazine unit.

AB - X-ray structural analysis of octakis(dimethylamino)porphyrazinato- metallo(II)·[60]fullerene complexes (M = Cu2+ and Ni2+) surprisingly revealed two totally different supramolecular structures, the first exhibiting a C(i) symmetric sandwich complex of two slightly dished porphyrazine units enclosing one fullerene sphere, the other featuring a noncentrosymmetric 1:1 complex with a strongly warped porphyrazine unit.

KW - Fullerenes

KW - Porphyrazines

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DO - 10.1002/(sici)1099-0682(200004)2000:4<593::aid-ejic593>3.0.co;2-n

M3 - Article

AN - SCOPUS:0034051743

SN - 1434-1948

SP - 593

EP - 596

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 4

ER -

C(i) symmetric and non-centrosymmetric crystalline complexes of [60]fullerene with octakis(dimethylamino)porphyrazinato-copper(II) and - nickel(II)

Abstract

Keywords

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