"clean reaction" strategy to approach a stable, green heptatwistacene containing a single terminal pyrene unit

Jinchong Xiao; Christos D. Malliakas; Yi Liu; Feng Zhou; Gang Li; Haibin Su; Mercouri G. Kanatzidis; Fred Wudl; Qichun Zhang

doi:10.1002/asia.201100910

"clean reaction" strategy to approach a stable, green heptatwistacene containing a single terminal pyrene unit

Jinchong Xiao, Christos D. Malliakas, Yi Liu, Feng Zhou, Gang Li, Haibin Su, Mercouri G. Kanatzidis, Fred Wudl, Qichun Zhang^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

99 Scopus citations

Abstract

Let's twist again: A "clean reaction" strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels-Alder reaction gives a new, stable, green heptatwistacene (see structure). The molecule has a twist angle of 23.49°, is very stable even in air, and has an optical band gap of 1.82 eV.

Original language	English (US)
Pages (from-to)	672-675
Number of pages	4
Journal	Chemistry - An Asian Journal
Volume	7
Issue number	4
DOIs	https://doi.org/10.1002/asia.201100910
State	Published - Apr 2012

Keywords

density functional theory
physical properties
polycycles
structure elucidation
twistacenes

ASJC Scopus subject areas

Biochemistry
Organic Chemistry

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10.1002/asia.201100910

Cite this

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abstract = "Let's twist again: A {"}clean reaction{"} strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels-Alder reaction gives a new, stable, green heptatwistacene (see structure). The molecule has a twist angle of 23.49°, is very stable even in air, and has an optical band gap of 1.82 eV.",

keywords = "density functional theory, physical properties, polycycles, structure elucidation, twistacenes",

author = "Jinchong Xiao and Malliakas, {Christos D.} and Yi Liu and Feng Zhou and Gang Li and Haibin Su and Kanatzidis, {Mercouri G.} and Fred Wudl and Qichun Zhang",

year = "2012",

month = apr,

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language = "English (US)",

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T1 - "clean reaction" strategy to approach a stable, green heptatwistacene containing a single terminal pyrene unit

AU - Xiao, Jinchong

AU - Malliakas, Christos D.

AU - Liu, Yi

AU - Zhou, Feng

AU - Li, Gang

AU - Su, Haibin

AU - Kanatzidis, Mercouri G.

AU - Wudl, Fred

AU - Zhang, Qichun

PY - 2012/4

Y1 - 2012/4

N2 - Let's twist again: A "clean reaction" strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels-Alder reaction gives a new, stable, green heptatwistacene (see structure). The molecule has a twist angle of 23.49°, is very stable even in air, and has an optical band gap of 1.82 eV.

AB - Let's twist again: A "clean reaction" strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels-Alder reaction gives a new, stable, green heptatwistacene (see structure). The molecule has a twist angle of 23.49°, is very stable even in air, and has an optical band gap of 1.82 eV.

KW - density functional theory

KW - physical properties

KW - polycycles

KW - structure elucidation

KW - twistacenes

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"clean reaction" strategy to approach a stable, green heptatwistacene containing a single terminal pyrene unit

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 846054: Experimental Crystal Structure Determination

Cite this

"clean reaction" strategy to approach a stable, green heptatwistacene containing a single terminal pyrene unit

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 846054: Experimental Crystal Structure Determination

Cite this