Cobalt-mediated approach for the synthesis of terpene-based hybrids

Elsa Álvaro, María C. De La Torre*, Miguel A. Sierra

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

(Matrix presented) Dicobalt-β-pinene hybrids of types I and II have been prepared using a Nicholas reaction between propargyl derivatives, obtained from commercial (1R)-(-)-myrtenal, and different aromatic nucleophiles. The method is suitable for the preparation of densely functionalized bio-organometallic natural product-based hybrids, as demonstrated by the preparation of a β-pinene-neoclerodane hybrid.

Original languageEnglish (US)
Pages (from-to)2381-2384
Number of pages4
JournalOrganic Letters
Volume5
Issue number14
DOIs
StatePublished - Jul 10 2003

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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