Cobalt-mediated approach for the synthesis of terpene-based hybrids

Elsa Álvaro; María C. De La Torre; Miguel A. Sierra

doi:10.1021/ol034483y

Cobalt-mediated approach for the synthesis of terpene-based hybrids

Elsa Álvaro, María C. De La Torre^*, Miguel A. Sierra

^*Corresponding author for this work

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Abstract

(Matrix presented) Dicobalt-β-pinene hybrids of types I and II have been prepared using a Nicholas reaction between propargyl derivatives, obtained from commercial (1R)-(-)-myrtenal, and different aromatic nucleophiles. The method is suitable for the preparation of densely functionalized bio-organometallic natural product-based hybrids, as demonstrated by the preparation of a β-pinene-neoclerodane hybrid.

Original language	English (US)
Pages (from-to)	2381-2384
Number of pages	4
Journal	Organic Letters
Volume	5
Issue number	14
DOIs	https://doi.org/10.1021/ol034483y
State	Published - Jul 10 2003

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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abstract = "(Matrix presented) Dicobalt-β-pinene hybrids of types I and II have been prepared using a Nicholas reaction between propargyl derivatives, obtained from commercial (1R)-(-)-myrtenal, and different aromatic nucleophiles. The method is suitable for the preparation of densely functionalized bio-organometallic natural product-based hybrids, as demonstrated by the preparation of a β-pinene-neoclerodane hybrid.",

author = "Elsa {\'A}lvaro and {De La Torre}, {Mar{\'i}a C.} and Sierra, {Miguel A.}",

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AU - Álvaro, Elsa

AU - De La Torre, María C.

AU - Sierra, Miguel A.

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Y1 - 2003/7/10

N2 - (Matrix presented) Dicobalt-β-pinene hybrids of types I and II have been prepared using a Nicholas reaction between propargyl derivatives, obtained from commercial (1R)-(-)-myrtenal, and different aromatic nucleophiles. The method is suitable for the preparation of densely functionalized bio-organometallic natural product-based hybrids, as demonstrated by the preparation of a β-pinene-neoclerodane hybrid.

AB - (Matrix presented) Dicobalt-β-pinene hybrids of types I and II have been prepared using a Nicholas reaction between propargyl derivatives, obtained from commercial (1R)-(-)-myrtenal, and different aromatic nucleophiles. The method is suitable for the preparation of densely functionalized bio-organometallic natural product-based hybrids, as demonstrated by the preparation of a β-pinene-neoclerodane hybrid.

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Cobalt-mediated approach for the synthesis of terpene-based hybrids

Abstract

ASJC Scopus subject areas

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