Comparison of the Stability of Iridium-(η2-Carbon Disulfide) and Iridium-(η2-Carbonyl Sulfide) Complexes

Thomas R. Gaffney, James A. Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

New complexes of the type IrCl(CO)(η2-SCY)(L)2 (Y = O, L = PMe2Ph, PMe3; Y = S, L = PMe3) have been prepared. Formation constants and values of ΔH and ΔS have been measured. The stability of a given complex toward dissociation of SCY is greater when L is a small, basic phosphine ligand, and the stability has also been correlated with the electron affinity of SCY.

Original languageEnglish (US)
Pages (from-to)2854-2856
Number of pages3
JournalInorganic chemistry
Volume21
Issue number7
DOIs
StatePublished - Jan 1 1982

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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