TY - JOUR
T1 - Complex formation between dibenzo-3n-crown-n ethers and the diquat dication
AU - Colquhoun, Howard M.
AU - Goodings, Eric P.
AU - Maud, John M.
AU - Stoddart, J. Fraser
AU - Williams, David J.
AU - Wolstenholme, John B.
PY - 1983
Y1 - 1983
N2 - An X-ray crystallographic investigation of the complex between the diquat dication and dibenzo-30-crown-10, [Diquat.DB30C10] [PF6]2, reveals gross structural features for host-guest complexes (I) and (II) in which weak [C-H ⋯ O] hydrogen bonding and charge transfer are the major components of host-guest binding; these same components are also responsible for the formation of stable and ordered 1:1 solution complexes between dibenzo-3n-crown-n (n = 9-12) and diquat bis(hexafluorophosphate) (2).
AB - An X-ray crystallographic investigation of the complex between the diquat dication and dibenzo-30-crown-10, [Diquat.DB30C10] [PF6]2, reveals gross structural features for host-guest complexes (I) and (II) in which weak [C-H ⋯ O] hydrogen bonding and charge transfer are the major components of host-guest binding; these same components are also responsible for the formation of stable and ordered 1:1 solution complexes between dibenzo-3n-crown-n (n = 9-12) and diquat bis(hexafluorophosphate) (2).
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U2 - 10.1039/c39830001140
DO - 10.1039/c39830001140
M3 - Article
AN - SCOPUS:37049099799
SP - 1140
EP - 1142
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
SN - 0022-4936
IS - 20
ER -