Complexing properties of a bisdianhydro-D-mannitolo-30-crown-10 derivative in the solution and solid states; X-ray crystal structure

Janet C. Metcalfe, J. Fraser Stoddart*, Geraint Jones, Thomas H. Crawshaw, Enrico Gavuzzo, David J. Williams

*Corresponding author for this work

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

X-Ray crystallography has revealed that the chiral 30-crown-10 derivative DD-(2) adopts a basketlike conformation when it forms a 1:1:1 complex with (S)-[PhCHMeNH3]+ ClO4- and H 2O in the solid state; 1H n.m.r. spectroscopy suggests that 1:1:1 complexes of this type between (i) DD-(2), R1NH 3+ cations, and H2O, and (ii) DD-(2), R 1NH3+ cations, and R2NH2 are also stable in solution.

Original languageEnglish (US)
Pages (from-to)432-434
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number9
DOIs
StatePublished - 1981

ASJC Scopus subject areas

  • Molecular Medicine

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