Composition Space of the (CuO, 1/2Nb2O5)/(HF)x·pyridine/H2O System. Structure and Synthesis of [pyH+]2[CuNb2(py)4O 2F10]2- and CuNb(py)4OF5

Paramasivan Halasyamani; Michael J. Willis; Charlotte L. Stern; Paul M. Lundquist; George K. Wong; Kenneth Poeppelmeier

Composition Space of the (CuO, 1/2Nb₂O₅)/(HF)_x·pyridine/H₂O System. Structure and Synthesis of [pyH⁺]₂[CuNb₂(py)₄O ₂F₁₀]^2- and CuNb(py)₄OF₅

Paramasivan Halasyamani, Michael J. Willis, Charlotte L. Stern, Paul M. Lundquist, George K. Wong, Kenneth Poeppelmeier^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

Single crystals of [pyH⁺]₂[CuNb₂(py)₄O ₂F₁₀]^2- and CuNb(py)4OF5 were synthesized in a (HF)₁·pyridine/pyridine/ water solution (150 °C, 24 h, autogeneous pressure) using CuO and Nb₂O as reagents. The compound [pyH⁺]₂[CuNb₂(py)O₂F] ^2-contains clusters of [CuNb₂(py)4O₂F₁₀]^2- anions linked through N-H⁺⋯F hydrogen bonds to the [pyH⁺ cations. In contrast CuNb(py)OF₅ is a unidimensional compound consisting only of chains, perpendicular to the c axis, of alternating [Cu(py)₄(O/F)_2/2]^{0 5+} and [NbF₄(O/F)_2/2]^{0 5-} octahedra. The chains change direction between the [110] and [110] every c/2. Crystal data for [pyH⁺]₂[CuNb₂(py)₄O ₂F₁₀]^2-: tetragonal, space group I4₁22 (No. 98), with a = 11.408(3) Å, c = 30.36(1) Å, and Z = 4. Crystal data for CuNb(py)₄OF₅: monoclinic, space group C2/c (No. 15), with a = 10.561(3) Å, b = 13.546(6) Å, c = 16.103(4) Å, β= 97.77(2)°, and Z = 4.

Original language	English (US)
Pages (from-to)	1367-1371
Number of pages	5
Journal	Inorganic Chemistry
Volume	35
Issue number	5
State	Published - Dec 1 1996

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Physical and Theoretical Chemistry
Inorganic Chemistry

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@article{9442260e60d645f08f350e9d2637b683,

title = "Composition Space of the (CuO, 1/2Nb2O5)/(HF)x·pyridine/H2O System. Structure and Synthesis of [pyH+]2[CuNb2(py)4O 2F10]2- and CuNb(py)4OF5",

abstract = "Single crystals of [pyH+]2[CuNb2(py)4O 2F10]2- and CuNb(py)4OF5 were synthesized in a (HF)1·pyridine/pyridine/ water solution (150 °C, 24 h, autogeneous pressure) using CuO and Nb2O as reagents. The compound [pyH+]2[CuNb2(py)O2F] 2-contains clusters of [CuNb2(py)4O2F10]2- anions linked through N-H+⋯F hydrogen bonds to the [pyH+ cations. In contrast CuNb(py)OF5 is a unidimensional compound consisting only of chains, perpendicular to the c axis, of alternating [Cu(py)4(O/F)2/2]0 5+ and [NbF4(O/F)2/2]0 5- octahedra. The chains change direction between the [110] and [110] every c/2. Crystal data for [pyH+]2[CuNb2(py)4O 2F10]2-: tetragonal, space group I4122 (No. 98), with a = 11.408(3) {\AA}, c = 30.36(1) {\AA}, and Z = 4. Crystal data for CuNb(py)4OF5: monoclinic, space group C2/c (No. 15), with a = 10.561(3) {\AA}, b = 13.546(6) {\AA}, c = 16.103(4) {\AA}, β= 97.77(2)°, and Z = 4.",

author = "Paramasivan Halasyamani and Willis, {Michael J.} and Stern, {Charlotte L.} and Lundquist, {Paul M.} and Wong, {George K.} and Kenneth Poeppelmeier",

year = "1996",

month = dec,

day = "1",

language = "English (US)",

volume = "35",

pages = "1367--1371",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Composition Space of the (CuO, 1/2Nb2O5)/(HF)x·pyridine/H2O System. Structure and Synthesis of [pyH+]2[CuNb2(py)4O 2F10]2- and CuNb(py)4OF5

AU - Halasyamani, Paramasivan

AU - Willis, Michael J.

AU - Stern, Charlotte L.

AU - Lundquist, Paul M.

AU - Wong, George K.

AU - Poeppelmeier, Kenneth

PY - 1996/12/1

Y1 - 1996/12/1

N2 - Single crystals of [pyH+]2[CuNb2(py)4O 2F10]2- and CuNb(py)4OF5 were synthesized in a (HF)1·pyridine/pyridine/ water solution (150 °C, 24 h, autogeneous pressure) using CuO and Nb2O as reagents. The compound [pyH+]2[CuNb2(py)O2F] 2-contains clusters of [CuNb2(py)4O2F10]2- anions linked through N-H+⋯F hydrogen bonds to the [pyH+ cations. In contrast CuNb(py)OF5 is a unidimensional compound consisting only of chains, perpendicular to the c axis, of alternating [Cu(py)4(O/F)2/2]0 5+ and [NbF4(O/F)2/2]0 5- octahedra. The chains change direction between the [110] and [110] every c/2. Crystal data for [pyH+]2[CuNb2(py)4O 2F10]2-: tetragonal, space group I4122 (No. 98), with a = 11.408(3) Å, c = 30.36(1) Å, and Z = 4. Crystal data for CuNb(py)4OF5: monoclinic, space group C2/c (No. 15), with a = 10.561(3) Å, b = 13.546(6) Å, c = 16.103(4) Å, β= 97.77(2)°, and Z = 4.

AB - Single crystals of [pyH+]2[CuNb2(py)4O 2F10]2- and CuNb(py)4OF5 were synthesized in a (HF)1·pyridine/pyridine/ water solution (150 °C, 24 h, autogeneous pressure) using CuO and Nb2O as reagents. The compound [pyH+]2[CuNb2(py)O2F] 2-contains clusters of [CuNb2(py)4O2F10]2- anions linked through N-H+⋯F hydrogen bonds to the [pyH+ cations. In contrast CuNb(py)OF5 is a unidimensional compound consisting only of chains, perpendicular to the c axis, of alternating [Cu(py)4(O/F)2/2]0 5+ and [NbF4(O/F)2/2]0 5- octahedra. The chains change direction between the [110] and [110] every c/2. Crystal data for [pyH+]2[CuNb2(py)4O 2F10]2-: tetragonal, space group I4122 (No. 98), with a = 11.408(3) Å, c = 30.36(1) Å, and Z = 4. Crystal data for CuNb(py)4OF5: monoclinic, space group C2/c (No. 15), with a = 10.561(3) Å, b = 13.546(6) Å, c = 16.103(4) Å, β= 97.77(2)°, and Z = 4.

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UR - http://www.scopus.com/inward/citedby.url?scp=0001822250&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0001822250

SN - 0020-1669

VL - 35

SP - 1367

EP - 1371

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 5

ER -

Composition Space of the (CuO, 1/2Nb₂O₅)/(HF)_x·pyridine/H₂O System. Structure and Synthesis of [pyH⁺]₂[CuNb₂(py)₄O ₂F₁₀]^2- and CuNb(py)₄OF₅

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