The temperature dependences of the 1H n.m.r. and broad-band decoupled 13C n.m.r. spectra of 126.96.36.199-tetrahydrodibenzo[a, d]cyclo-octene (4) have been interpreted in terms of the interconversion of chair- and boat-like conformations. Strain energy calculations on selected conformations of this hydrocarbon (4) have led to useful correlations between calculated and experimental thermodynamic parameters.
|Original language||English (US)|
|Number of pages||7|
|Journal||Journal of the Chemical Society, Perkin Transactions 1|
|State||Published - 1978|
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