Conformational diastereoisomerism in a chiral pretzelane

Yi Liu, Scott A. Vignon, Xiyun Zhang, K. N. Houk, J. Fraser Stoddart*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

21 Scopus citations

Abstract

The introduction of a stereogenic center by a stereospecific synthesis into an optically active, donor-acceptor pretzelane, that exhibits helicity as well as fixed chirality, leads to a marked preference for one conformational diastereoisomer over the other in both acetone and dimethylsulfoxide that can be understood from computational models.

Original languageEnglish (US)
Pages (from-to)3927-3929
Number of pages3
JournalChemical Communications
Issue number31
DOIs
StatePublished - Aug 21 2005

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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