Control over catenation in pillared paddlewheel metal-organic framework materials via solvent-assisted linker exchange

Wojciech Bury; David Fairen-Jimenez; Marianne B. Lalonde; Randall Q. Snurr; Omar K. Farha; Joseph T. Hupp

doi:10.1021/cm303749m

Control over catenation in pillared paddlewheel metal-organic framework materials via solvent-assisted linker exchange

Wojciech Bury, David Fairen-Jimenez, Marianne B. Lalonde, Randall Q. Snurr, Omar K. Farha^*, Joseph T. Hupp

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

127 Scopus citations

Abstract

Control over catenation in a pillared paddlewheel metal-organic framework was achieved via solvent-assisted linker exchange. The linker exchange was demonstrated on the noncatenated structure of DO-MOF, by using 4,4′-bipyridine (L4) and 4,4′-azobis(pyridine) (L5) as linkers, leading to noncatenated materials SALEM-3 and SALEM-4. The de novo synthesized analogues of SALEM-3 and SALEM-4 can only be obtained as 2-fold interpenetrated frameworks. The reaction progress of the linker exchange was monitored by NMR spectroscopy, and structure and framework catenation were characterized by powder X-ray diffraction and thermogravimetric methods.

Original language	English (US)
Pages (from-to)	739-744
Number of pages	6
Journal	Chemistry of Materials
Volume	25
Issue number	5
DOIs	https://doi.org/10.1021/cm303749m
State	Published - Mar 12 2013

Keywords

SALE
catenation
linker exchange
metal-organic frameworks

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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10.1021/cm303749m

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abstract = "Control over catenation in a pillared paddlewheel metal-organic framework was achieved via solvent-assisted linker exchange. The linker exchange was demonstrated on the noncatenated structure of DO-MOF, by using 4,4′-bipyridine (L4) and 4,4′-azobis(pyridine) (L5) as linkers, leading to noncatenated materials SALEM-3 and SALEM-4. The de novo synthesized analogues of SALEM-3 and SALEM-4 can only be obtained as 2-fold interpenetrated frameworks. The reaction progress of the linker exchange was monitored by NMR spectroscopy, and structure and framework catenation were characterized by powder X-ray diffraction and thermogravimetric methods.",

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T1 - Control over catenation in pillared paddlewheel metal-organic framework materials via solvent-assisted linker exchange

AU - Bury, Wojciech

AU - Fairen-Jimenez, David

AU - Lalonde, Marianne B.

AU - Snurr, Randall Q.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

PY - 2013/3/12

Y1 - 2013/3/12

N2 - Control over catenation in a pillared paddlewheel metal-organic framework was achieved via solvent-assisted linker exchange. The linker exchange was demonstrated on the noncatenated structure of DO-MOF, by using 4,4′-bipyridine (L4) and 4,4′-azobis(pyridine) (L5) as linkers, leading to noncatenated materials SALEM-3 and SALEM-4. The de novo synthesized analogues of SALEM-3 and SALEM-4 can only be obtained as 2-fold interpenetrated frameworks. The reaction progress of the linker exchange was monitored by NMR spectroscopy, and structure and framework catenation were characterized by powder X-ray diffraction and thermogravimetric methods.

AB - Control over catenation in a pillared paddlewheel metal-organic framework was achieved via solvent-assisted linker exchange. The linker exchange was demonstrated on the noncatenated structure of DO-MOF, by using 4,4′-bipyridine (L4) and 4,4′-azobis(pyridine) (L5) as linkers, leading to noncatenated materials SALEM-3 and SALEM-4. The de novo synthesized analogues of SALEM-3 and SALEM-4 can only be obtained as 2-fold interpenetrated frameworks. The reaction progress of the linker exchange was monitored by NMR spectroscopy, and structure and framework catenation were characterized by powder X-ray diffraction and thermogravimetric methods.

KW - SALE

KW - catenation

KW - linker exchange

KW - metal-organic frameworks

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Control over catenation in pillared paddlewheel metal-organic framework materials via solvent-assisted linker exchange

Abstract

Keywords

ASJC Scopus subject areas

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