Controlling the Lattice Parameters of Gold Nanoparticle FCC Crystals with Duplex DNA Linkers

Haley D. Hill; Robert J. Macfarlane; Andrew J. Senesi; Byeongdu Lee; Sung Yong Park; Chad A. Mirkin

doi:10.1201/9781003056690-43

Controlling the Lattice Parameters of Gold Nanoparticle FCC Crystals with Duplex DNA Linkers

Haley D. Hill, Robert J. Macfarlane, Andrew J. Senesi, Byeongdu Lee, Sung Yong Park, Chad A. Mirkin^*

^*Corresponding author for this work

Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

764DNA-functionalized gold nanoparticles can be used to induce the formation and control the unit cell parameters of highly ordered face-centered cubic crystal lattices. Nanoparticle spacing increases linearly with longer DNA interconnect length, yielding maximum unit cell parameters of 77 nm and 0.52% inorganic-filled space for the DNA constructs studied. In general, we show that longer DNA connections result in a decrease in the overall crystallinity and order of the lattice due to greater conformational flexibility.

Original language	English (US)
Title of host publication	Spherical Nucleic Acids
Subtitle of host publication	Volume 2
Publisher	Jenny Stanford Publishing
Pages	763-773
Number of pages	11
Volume	2
ISBN (Electronic)	9781000092363
ISBN (Print)	9789814877220
DOIs	https://doi.org/10.1201/9781003056690-43
State	Published - Jan 1 2021

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology
General Engineering
General Chemistry

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title = "Controlling the Lattice Parameters of Gold Nanoparticle FCC Crystals with Duplex DNA Linkers",

abstract = "764DNA-functionalized gold nanoparticles can be used to induce the formation and control the unit cell parameters of highly ordered face-centered cubic crystal lattices. Nanoparticle spacing increases linearly with longer DNA interconnect length, yielding maximum unit cell parameters of 77 nm and 0.52\% inorganic-filled space for the DNA constructs studied. In general, we show that longer DNA connections result in a decrease in the overall crystallinity and order of the lattice due to greater conformational flexibility.",

author = "Hill, \{Haley D.\} and Macfarlane, \{Robert J.\} and Senesi, \{Andrew J.\} and Byeongdu Lee and Park, \{Sung Yong\} and Mirkin, \{Chad A.\}",

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doi = "10.1201/9781003056690-43",

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AU - Hill, Haley D.

AU - Macfarlane, Robert J.

AU - Senesi, Andrew J.

AU - Lee, Byeongdu

AU - Park, Sung Yong

AU - Mirkin, Chad A.

PY - 2021/1/1

Y1 - 2021/1/1

N2 - 764DNA-functionalized gold nanoparticles can be used to induce the formation and control the unit cell parameters of highly ordered face-centered cubic crystal lattices. Nanoparticle spacing increases linearly with longer DNA interconnect length, yielding maximum unit cell parameters of 77 nm and 0.52% inorganic-filled space for the DNA constructs studied. In general, we show that longer DNA connections result in a decrease in the overall crystallinity and order of the lattice due to greater conformational flexibility.

AB - 764DNA-functionalized gold nanoparticles can be used to induce the formation and control the unit cell parameters of highly ordered face-centered cubic crystal lattices. Nanoparticle spacing increases linearly with longer DNA interconnect length, yielding maximum unit cell parameters of 77 nm and 0.52% inorganic-filled space for the DNA constructs studied. In general, we show that longer DNA connections result in a decrease in the overall crystallinity and order of the lattice due to greater conformational flexibility.

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Controlling the Lattice Parameters of Gold Nanoparticle FCC Crystals with Duplex DNA Linkers

Abstract

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