TY - JOUR
T1 - Controlling the properties of thermoplastic starch films with hydrogen bonding plasticizers
AU - Chen, Yu Ling
AU - Shull, Kenneth R.
N1 - Funding Information:
This work was performed under the financial assistance award 70NANB19H005 from U.S. Department of Commerce, National Institute of Standards and Technology as part of the Center for Hierarchical Materials Design (CHiMaD). X-ray diffraction experiments were performed at the Jerome B.Cohen X-Ray Diffraction Facility supported by the MRSEC program of the National Science Foundation ( DMR-1720139 ) at the Materials Research Center of Northwestern University and the Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource (NSF ECCS-2025633).
Publisher Copyright:
© 2023 The Author(s)
PY - 2023/6
Y1 - 2023/6
N2 - Four deep eutectic solvents were used to produce plasticized thermoplastic starch films by a solution casting method. The mechanical properties of thin films, the stability of these properties over time, and the effects of humidity were investigated with the quartz crystal microbalance. The crystallinity, glass transition temperature, modulus and elongation at break for thicker films was measured using a combination of x-ray diffraction, differential scanning calorimetry and tensile testing. The films had very low glass transition temperatures (-50 ∘C or lower), with mechanical properties determined by the crystallinity of the films. The crystallinity did not change significantly over a period of one week, giving materials with a stable mechanical response. Deep eutectic solvents containing ammonium acetate, glycerol, and urea produced films with a crystalline structure that was much more stable at high humidity values than films plasticized only with glycerol or a traditional ionic liquid. These effects are attributed to the complex hydrogen bonding interactions between the different components of the deep eutectic solvents, and between these components and the starch polymer.
AB - Four deep eutectic solvents were used to produce plasticized thermoplastic starch films by a solution casting method. The mechanical properties of thin films, the stability of these properties over time, and the effects of humidity were investigated with the quartz crystal microbalance. The crystallinity, glass transition temperature, modulus and elongation at break for thicker films was measured using a combination of x-ray diffraction, differential scanning calorimetry and tensile testing. The films had very low glass transition temperatures (-50 ∘C or lower), with mechanical properties determined by the crystallinity of the films. The crystallinity did not change significantly over a period of one week, giving materials with a stable mechanical response. Deep eutectic solvents containing ammonium acetate, glycerol, and urea produced films with a crystalline structure that was much more stable at high humidity values than films plasticized only with glycerol or a traditional ionic liquid. These effects are attributed to the complex hydrogen bonding interactions between the different components of the deep eutectic solvents, and between these components and the starch polymer.
KW - Crystallinity
KW - Deep eutectic solvents
KW - Humidity
KW - Plasticization
KW - Stability
KW - Thermoplastic starch
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U2 - 10.1016/j.carpta.2023.100291
DO - 10.1016/j.carpta.2023.100291
M3 - Article
AN - SCOPUS:85147566798
SN - 2666-8939
VL - 5
JO - Carbohydrate Polymer Technologies and Applications
JF - Carbohydrate Polymer Technologies and Applications
M1 - 100291
ER -