Conversion of a Re(IV) tetrahedral cluster to.a Re(III) octahedral cluster: Synthesis of [(CH3)C(NH2)2]4 [Re6Se8(CN)6] by a solvothermal route

Mehtap Emirdag-Eanes; James A. Ibers

doi:10.1021/ic020433y

Conversion of a Re(IV) tetrahedral cluster to.a Re(III) octahedral cluster: Synthesis of [(CH₃)C(NH₂)₂]₄ [Re₆Se₈(CN)₆] by a solvothermal route

Mehtap Emirdag-Eanes, James A. Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

The compound [(CH₃)C(NH₂)₂]₄ [Re₆Se₈(CN)₆] has been synthesized by the reaction at 200°C for 3 days of Re₄Te₄(TeCl₂)₄Cl₈, KSeCN, and NH4Cl in superheated acetonitrile. This compound crystallizes in the space group C2/c of the monoclinic system with four formula units in a cell of dimensions a = 20.3113(14) Å, b = 10.1332(7) Å, c = 19.9981(14) Å, β = 106.754(1)°, V = 3941.3(5) Å³ (T = 153 K). The [Re₆Se₈(CN)₆]^4- anion comprises an Re₆ octahedron face capped by μ₃-Se atoms, with each Re atom liganded by a CN group. The anions and cations are connected by an extensive network of hydrogen bonds. The conversion of a Re(IV) tetrahedral cluster to a Re(III) octahedral cluster appears to be unprecedented.

Original language	English (US)
Pages (from-to)	6170-6171
Number of pages	2
Journal	Inorganic chemistry
Volume	41
Issue number	24
DOIs	https://doi.org/10.1021/ic020433y
State	Published - Dec 2 2002

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

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10.1021/ic020433y

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title = "Conversion of a Re(IV) tetrahedral cluster to.a Re(III) octahedral cluster: Synthesis of [(CH3)C(NH2)2]4 [Re6Se8(CN)6] by a solvothermal route",

abstract = "The compound [(CH3)C(NH2)2]4 [Re6Se8(CN)6] has been synthesized by the reaction at 200°C for 3 days of Re4Te4(TeCl2)4Cl8, KSeCN, and NH4Cl in superheated acetonitrile. This compound crystallizes in the space group C2/c of the monoclinic system with four formula units in a cell of dimensions a = 20.3113(14) {\AA}, b = 10.1332(7) {\AA}, c = 19.9981(14) {\AA}, β = 106.754(1)°, V = 3941.3(5) {\AA}3 (T = 153 K). The [Re6Se8(CN)6]4- anion comprises an Re6 octahedron face capped by μ3-Se atoms, with each Re atom liganded by a CN group. The anions and cations are connected by an extensive network of hydrogen bonds. The conversion of a Re(IV) tetrahedral cluster to a Re(III) octahedral cluster appears to be unprecedented.",

author = "Mehtap Emirdag-Eanes and Ibers, {James A.}",

year = "2002",

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doi = "10.1021/ic020433y",

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issn = "0020-1669",

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T1 - Conversion of a Re(IV) tetrahedral cluster to.a Re(III) octahedral cluster

T2 - Synthesis of [(CH3)C(NH2)2]4 [Re6Se8(CN)6] by a solvothermal route

AU - Emirdag-Eanes, Mehtap

AU - Ibers, James A.

PY - 2002/12/2

Y1 - 2002/12/2

N2 - The compound [(CH3)C(NH2)2]4 [Re6Se8(CN)6] has been synthesized by the reaction at 200°C for 3 days of Re4Te4(TeCl2)4Cl8, KSeCN, and NH4Cl in superheated acetonitrile. This compound crystallizes in the space group C2/c of the monoclinic system with four formula units in a cell of dimensions a = 20.3113(14) Å, b = 10.1332(7) Å, c = 19.9981(14) Å, β = 106.754(1)°, V = 3941.3(5) Å3 (T = 153 K). The [Re6Se8(CN)6]4- anion comprises an Re6 octahedron face capped by μ3-Se atoms, with each Re atom liganded by a CN group. The anions and cations are connected by an extensive network of hydrogen bonds. The conversion of a Re(IV) tetrahedral cluster to a Re(III) octahedral cluster appears to be unprecedented.

AB - The compound [(CH3)C(NH2)2]4 [Re6Se8(CN)6] has been synthesized by the reaction at 200°C for 3 days of Re4Te4(TeCl2)4Cl8, KSeCN, and NH4Cl in superheated acetonitrile. This compound crystallizes in the space group C2/c of the monoclinic system with four formula units in a cell of dimensions a = 20.3113(14) Å, b = 10.1332(7) Å, c = 19.9981(14) Å, β = 106.754(1)°, V = 3941.3(5) Å3 (T = 153 K). The [Re6Se8(CN)6]4- anion comprises an Re6 octahedron face capped by μ3-Se atoms, with each Re atom liganded by a CN group. The anions and cations are connected by an extensive network of hydrogen bonds. The conversion of a Re(IV) tetrahedral cluster to a Re(III) octahedral cluster appears to be unprecedented.

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Conversion of a Re(IV) tetrahedral cluster to.a Re(III) octahedral cluster: Synthesis of [(CH₃)C(NH₂)₂]₄ [Re₆Se₈(CN)₆] by a solvothermal route

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CCDC 201091: Experimental Crystal Structure Determination

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Conversion of a Re(IV) tetrahedral cluster to.a Re(III) octahedral cluster: Synthesis of [(CH3)C(NH2)2]4 [Re6Se8(CN)6] by a solvothermal route

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CCDC 201091: Experimental Crystal Structure Determination

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Conversion of a Re(IV) tetrahedral cluster to.a Re(III) octahedral cluster: Synthesis of [(CH₃)C(NH₂)₂]₄ [Re₆Se₈(CN)₆] by a solvothermal route