Copper derivatives of tetrathiafulvalene

A. R. Siedle*, G. A. Candela, T. F. Finnegan, R. P. Van Duyne, T. Cape, G. F. Kokoszka, P. M. Woyciesjes

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

Oxidation of tetrathiafulvalene with CuCl2.2H2O in ethanol produced the mixed valence metallotetrathia-ethylene (TTF) 3(CuCl2)5 containing both TTF +· and TTF2+, which was converted into (TTF) 2 CuCl4 on dissolution in hot acetonitrile while the CuCl42- and BF4- salts of TTF 2+ were prepared using CuCl2·2H2O and Cu(BF4)2 in acetonitrile; resonance Raman spectroscopy was used to probe the oxidation state of TTF in these copper metallotetrathiafulvalenes, and e.s.r. and magnetic susceptibility data indicate the presence of three-dimensional magnetic interactions in the TTF+ and TTF2+ CuCl42- salts.

Original languageEnglish (US)
Pages (from-to)69-70
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number2
DOIs
StatePublished - 1978

ASJC Scopus subject areas

  • Molecular Medicine

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