Counterion Dependent Structural Diversity in Silver Polyselenides; Structures of the New Complex Anions [Ag(Se4)] 44⊖, [Ag(Se5)] nn⊖ and [Ag4(Se4)3]2⊖

Mercouri G. Kanatzidis*, Song‐Ping ‐P Huang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

37 Scopus citations

Abstract

Large cations such as Ph4P and Pr4N favor a trigonal planar coordination, small ones such as Me4N a tetrahedral coordination of Ag in silver polyselenides. In the novel complex {[Me4N][Ag(Se5)]}n one‐dimensional infinite [Ag(Se5)] nn⊖ macroanions are present in which the Se 52⊖ ligands bridge three Ag atoms (see 1). (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)1513-1514
Number of pages2
JournalAngewandte Chemie International Edition in English
Volume28
Issue number11
DOIs
StatePublished - Jan 1 1989

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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