Counterion Dependent Structural Diversity in Silver Polyselenides; Structures of the New Complex Anions [Ag(Se4)] 44⊖, [Ag(Se5)] nn⊖ and [Ag4(Se4)3]2⊖

Mercouri G. Kanatzidis; Song‐Ping ‐P Huang

doi:10.1002/anie.198915131

Counterion Dependent Structural Diversity in Silver Polyselenides; Structures of the New Complex Anions [Ag(Se₄)] 44⊖, [Ag(Se₅)] nn⊖ and [Ag₄(Se₄)₃]^2⊖

Mercouri G. Kanatzidis^*, Song‐Ping ‐P Huang

^*Corresponding author for this work

Chemistry

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39 Scopus citations

Abstract

Large cations such as Ph₄P^⊕ and Pr₄N^⊕ favor a trigonal planar coordination, small ones such as Me₄N^⊕ a tetrahedral coordination of Ag^⊕ in silver polyselenides. In the novel complex {[Me₄N][Ag(Se₅)]}_n one‐dimensional infinite [Ag(Se₅)] nn⊖ macroanions are present in which the Se 52⊖ ligands bridge three Ag atoms (see 1). (Figure Presented.)

Original language	English (US)
Pages (from-to)	1513-1514
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	28
Issue number	11
DOIs	https://doi.org/10.1002/anie.198915131
State	Published - Nov 1989

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.198915131

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title = "Counterion Dependent Structural Diversity in Silver Polyselenides; Structures of the New Complex Anions [Ag(Se4)] 44⊖, [Ag(Se5)] nn⊖ and [Ag4(Se4)3]2⊖",

abstract = "Large cations such as Ph4P⊕ and Pr4N⊕ favor a trigonal planar coordination, small ones such as Me4N⊕ a tetrahedral coordination of Ag⊕ in silver polyselenides. In the novel complex {[Me4N][Ag(Se5)]}n one‐dimensional infinite [Ag(Se5)] nn⊖ macroanions are present in which the Se 52⊖ ligands bridge three Ag atoms (see 1). (Figure Presented.)",

author = "Kanatzidis, {Mercouri G.} and Huang, {Song‐Ping ‐P}",

year = "1989",

month = nov,

doi = "10.1002/anie.198915131",

language = "English (US)",

volume = "28",

pages = "1513--1514",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Ltd",

number = "11",

}

Counterion Dependent Structural Diversity in Silver Polyselenides; Structures of the New Complex Anions [Ag(Se₄)] 44⊖, [Ag(Se₅)] nn⊖ and [Ag₄(Se₄)₃]^2⊖. / Kanatzidis, Mercouri G.; Huang, Song‐Ping ‐P.
In: Angewandte Chemie International Edition in English, Vol. 28, No. 11, 11.1989, p. 1513-1514.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Counterion Dependent Structural Diversity in Silver Polyselenides; Structures of the New Complex Anions [Ag(Se4)] 44⊖, [Ag(Se5)] nn⊖ and [Ag4(Se4)3]2⊖

AU - Kanatzidis, Mercouri G.

AU - Huang, Song‐Ping ‐P

PY - 1989/11

Y1 - 1989/11

N2 - Large cations such as Ph4P⊕ and Pr4N⊕ favor a trigonal planar coordination, small ones such as Me4N⊕ a tetrahedral coordination of Ag⊕ in silver polyselenides. In the novel complex {[Me4N][Ag(Se5)]}n one‐dimensional infinite [Ag(Se5)] nn⊖ macroanions are present in which the Se 52⊖ ligands bridge three Ag atoms (see 1). (Figure Presented.)

AB - Large cations such as Ph4P⊕ and Pr4N⊕ favor a trigonal planar coordination, small ones such as Me4N⊕ a tetrahedral coordination of Ag⊕ in silver polyselenides. In the novel complex {[Me4N][Ag(Se5)]}n one‐dimensional infinite [Ag(Se5)] nn⊖ macroanions are present in which the Se 52⊖ ligands bridge three Ag atoms (see 1). (Figure Presented.)

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JO - Angewandte Chemie International Edition in English

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Counterion Dependent Structural Diversity in Silver Polyselenides; Structures of the New Complex Anions [Ag(Se₄)] 44⊖, [Ag(Se₅)] nn⊖ and [Ag₄(Se₄)₃]^2⊖

Abstract

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