Abstract
Large cations such as Ph4P⊕ and Pr4N⊕ favor a trigonal planar coordination, small ones such as Me4N⊕ a tetrahedral coordination of Ag⊕ in silver polyselenides. In the novel complex {[Me4N][Ag(Se5)]}n one‐dimensional infinite [Ag(Se5)] nn⊖ macroanions are present in which the Se 52⊖ ligands bridge three Ag atoms (see 1). (Figure Presented.)
Original language | English (US) |
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Pages (from-to) | 1513-1514 |
Number of pages | 2 |
Journal | Angewandte Chemie International Edition in English |
Volume | 28 |
Issue number | 11 |
DOIs | |
State | Published - Nov 1989 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)