Covalent bonding and the neutron magnetic form factor of the Mn2+ Ion

A. J. Freeman; D. E. Ellis

doi:10.1103/PhysRevLett.24.516

Covalent bonding and the neutron magnetic form factor of the Mn2+ Ion

A. J. Freeman^*, D. E. Ellis

^*Corresponding author for this work

Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Fully variational unrestricted Hartree-Fock calculations for the (MnF6)4- cluster are reported. Charge and spin densities are analyzed and shown to result in a neutron magnetic form factor which is contracted relative to the free-ion value in agreement with experiment but contrary to predictions of simple covalent-bonding theory.

Original language	English (US)
Pages (from-to)	516-520
Number of pages	5
Journal	Physical Review Letters
Volume	24
Issue number	10
DOIs	https://doi.org/10.1103/PhysRevLett.24.516
State	Published - Jan 1 1970

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Physics and Astronomy(all)

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10.1103/PhysRevLett.24.516

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title = "Covalent bonding and the neutron magnetic form factor of the Mn2+ Ion",

abstract = "Fully variational unrestricted Hartree-Fock calculations for the (MnF6)4- cluster are reported. Charge and spin densities are analyzed and shown to result in a neutron magnetic form factor which is contracted relative to the free-ion value in agreement with experiment but contrary to predictions of simple covalent-bonding theory.",

author = "Freeman, {A. J.} and Ellis, {D. E.}",

year = "1970",

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doi = "10.1103/PhysRevLett.24.516",

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AU - Freeman, A. J.

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AB - Fully variational unrestricted Hartree-Fock calculations for the (MnF6)4- cluster are reported. Charge and spin densities are analyzed and shown to result in a neutron magnetic form factor which is contracted relative to the free-ion value in agreement with experiment but contrary to predictions of simple covalent-bonding theory.

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Covalent bonding and the neutron magnetic form factor of the Mn2+ Ion

Abstract

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