Covalent surface modification of a metal-organic framework: Selective surface engineering via CuI-catalyzed Huisgen cycloaddition

Tendai Gadzikwa; Guang Lu; Charlotte L. Stern; Scott R. Wilson; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1039/b805101a

Covalent surface modification of a metal-organic framework: Selective surface engineering via Cu^I-catalyzed Huisgen cycloaddition

Tendai Gadzikwa, Guang Lu, Charlotte L. Stern, Scott R. Wilson, Joseph T. Hupp, Sonbinh T. Nguyen

Chemistry

Research output: Contribution to journal › Article › peer-review

140 Scopus citations

Abstract

A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via'click chemistry', in a demonstration of selective post-synthesis functionalization.

Original language	English (US)
Pages (from-to)	5493-5495
Number of pages	3
Journal	Chemical Communications
Issue number	43
DOIs	https://doi.org/10.1039/b805101a
State	Published - Nov 17 2008

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b805101a

Cite this

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title = "Covalent surface modification of a metal-organic framework: Selective surface engineering via CuI-catalyzed Huisgen cycloaddition",

abstract = "A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via'click chemistry', in a demonstration of selective post-synthesis functionalization.",

author = "Tendai Gadzikwa and Guang Lu and Stern, {Charlotte L.} and Wilson, {Scott R.} and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.}",

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AU - Gadzikwa, Tendai

AU - Lu, Guang

AU - Stern, Charlotte L.

AU - Wilson, Scott R.

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

PY - 2008/11/17

Y1 - 2008/11/17

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AB - A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via'click chemistry', in a demonstration of selective post-synthesis functionalization.

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Covalent surface modification of a metal-organic framework: Selective surface engineering via Cu^I-catalyzed Huisgen cycloaddition

Abstract

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CCDC 682857: Experimental Crystal Structure Determination

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Covalent surface modification of a metal-organic framework: Selective surface engineering via CuI-catalyzed Huisgen cycloaddition

Abstract

ASJC Scopus subject areas

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CCDC 682857: Experimental Crystal Structure Determination

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Covalent surface modification of a metal-organic framework: Selective surface engineering via Cu^I-catalyzed Huisgen cycloaddition