Crosslinked poly(amido-amine)s as superior matrices for chemical incorporation of highly efficient organic nonlinear optical dyes

Alessandro Abbotto; Luca Beverina; Giberto Chirico; Antonio Facchetti; Paolo Ferruti; Manuela Gilberti; Giorgio A. Pagani

doi:10.1002/marc.200390057

Crosslinked poly(amido-amine)s as superior matrices for chemical incorporation of highly efficient organic nonlinear optical dyes

Alessandro Abbotto, Luca Beverina, Giberto Chirico, Antonio Facchetti, Paolo Ferruti, Manuela Gilberti, Giorgio A. Pagani^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

We report on the synthesis and characterization of new crosslinked polymeric matrices, pertaining to the class of poly(amido-amine)s (PAAs), functionalized with highly performing nonlinear optical (NLO) heterocycle-based dyes as side-chain substituents. Linear, soluble, and highly crosslinked NLO-functionalized PAA networks can be easily prepared under mild conditions. The wide-ranging tunability of optical and mechanical properties of these matrices makes them a superior alternative to conventional high-T_g thermoplastic polymers.

Original language	English (US)
Pages (from-to)	397-402
Number of pages	6
Journal	Macromolecular Rapid Communications
Volume	24
Issue number	5-6
DOIs	https://doi.org/10.1002/marc.200390057
State	Published - Apr 17 2003

Keywords

Crosslinking
Fluorescence
Functionalization of polymers
NLO
UV-vis spectroscopy

ASJC Scopus subject areas

Polymers and Plastics
Organic Chemistry
Materials Chemistry

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title = "Crosslinked poly(amido-amine)s as superior matrices for chemical incorporation of highly efficient organic nonlinear optical dyes",

abstract = "We report on the synthesis and characterization of new crosslinked polymeric matrices, pertaining to the class of poly(amido-amine)s (PAAs), functionalized with highly performing nonlinear optical (NLO) heterocycle-based dyes as side-chain substituents. Linear, soluble, and highly crosslinked NLO-functionalized PAA networks can be easily prepared under mild conditions. The wide-ranging tunability of optical and mechanical properties of these matrices makes them a superior alternative to conventional high-Tg thermoplastic polymers.",

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T1 - Crosslinked poly(amido-amine)s as superior matrices for chemical incorporation of highly efficient organic nonlinear optical dyes

AU - Abbotto, Alessandro

AU - Beverina, Luca

AU - Chirico, Giberto

AU - Facchetti, Antonio

AU - Ferruti, Paolo

AU - Gilberti, Manuela

AU - Pagani, Giorgio A.

PY - 2003/4/17

Y1 - 2003/4/17

N2 - We report on the synthesis and characterization of new crosslinked polymeric matrices, pertaining to the class of poly(amido-amine)s (PAAs), functionalized with highly performing nonlinear optical (NLO) heterocycle-based dyes as side-chain substituents. Linear, soluble, and highly crosslinked NLO-functionalized PAA networks can be easily prepared under mild conditions. The wide-ranging tunability of optical and mechanical properties of these matrices makes them a superior alternative to conventional high-Tg thermoplastic polymers.

AB - We report on the synthesis and characterization of new crosslinked polymeric matrices, pertaining to the class of poly(amido-amine)s (PAAs), functionalized with highly performing nonlinear optical (NLO) heterocycle-based dyes as side-chain substituents. Linear, soluble, and highly crosslinked NLO-functionalized PAA networks can be easily prepared under mild conditions. The wide-ranging tunability of optical and mechanical properties of these matrices makes them a superior alternative to conventional high-Tg thermoplastic polymers.

KW - Crosslinking

KW - Fluorescence

KW - Functionalization of polymers

KW - NLO

KW - UV-vis spectroscopy

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DO - 10.1002/marc.200390057

M3 - Article

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JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 5-6

ER -

Crosslinked poly(amido-amine)s as superior matrices for chemical incorporation of highly efficient organic nonlinear optical dyes

Abstract

Keywords

ASJC Scopus subject areas

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